Microgel formation in the free radical crosslinking copolymerization of methyl methacrylate (MMA) and ethylene glycol dimethcrylate (EGDMA)
Conference
·
OSTI ID:602992
- Ohio State Univ., Columbus, OH (United States)
The formation of heterogeneous structure through intramolecular reaction is an important feature in the free radical crosslinking copolymerization of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). Such structure formation affects not only the curing behavior but also the rheological changes of the resin. In this work, the effect of co-monomer composition on the reaction kinetics, rheological changes and microgel formation of MMA-EGDMA copolymerization was studied. A percolation model was adopted to simulate such monovinyl-divinyl reactions.
- OSTI ID:
- 602992
- Report Number(s):
- CONF-961108--
- Country of Publication:
- United States
- Language:
- English
Similar Records
Properties of radiation cured vinyl-divinyl copolymers. Part I. Thermomechanical properties of crosslinked methyl methacrylate polymers
A novel crosslinker for UV copolymerization of N-vinyl pyrrolidone and methacrylates
Accelerated radiation polymerization of vinyl-divinyl comonomer systems. IV. Influence of molecular bridge length in divinyl monomer
Journal Article
·
Mon Dec 31 23:00:00 EST 1979
· J. Radiat. Curing; (United States)
·
OSTI ID:5345221
A novel crosslinker for UV copolymerization of N-vinyl pyrrolidone and methacrylates
Conference
·
Thu Dec 30 23:00:00 EST 1993
·
OSTI ID:141800
Accelerated radiation polymerization of vinyl-divinyl comonomer systems. IV. Influence of molecular bridge length in divinyl monomer
Journal Article
·
Sun Oct 01 00:00:00 EDT 1978
· J. Radiat. Curing; (United States)
·
OSTI ID:5377923