Diluent degradation products in the Purex solvent
Conference
·
OSTI ID:6017724
A number of laboratory tests were conducted in which various impurities, known to be present in degraded Purex solvent, were injected into fresh solvent samples and the effects of these impurities tested in an operating miniature pulse column and in batch contactors. Common fission product elements which interfere in the Purex process were spiked with radiotracers and added to the aqueous phase samples with which the test solvents were contacted. Process controls and blanks were used to verify test data. Periodically, samples of the organic phase were withdrawn for analyses by radiochemical means. From the data obtained, a number of theories were postulated on the mechanisms by which diluent degradation products interfere in the Purex process.
- Research Organization:
- Allied-General Nuclear Services, Barnwell, SC (USA)
- DOE Contract Number:
- AC09-78ET35900
- OSTI ID:
- 6017724
- Report Number(s):
- AGNS-35900-CONF-180; CONF-830633-5; ON: DE83016381
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
050800* -- Nuclear Fuels-- Spent Fuels Reprocessing
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
AMSCO
BUTYL PHOSPHATES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DECOMPOSITION
ESTERS
IMPURITIES
KINETICS
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANIC SOLVENTS
PHOSPHORIC ACID ESTERS
PUREX PROCESS
REACTION KINETICS
REPROCESSING
SEPARATION PROCESSES
SOLVENTS
TBP
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
AMSCO
BUTYL PHOSPHATES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DECOMPOSITION
ESTERS
IMPURITIES
KINETICS
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANIC SOLVENTS
PHOSPHORIC ACID ESTERS
PUREX PROCESS
REACTION KINETICS
REPROCESSING
SEPARATION PROCESSES
SOLVENTS
TBP