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Chemistry of gaseous, lower valent actinide halides: Technical progress report

Technical Report ·
OSTI ID:6014757
;

Gaseous equilibria in the Th-Br system were investigated; bond dissociation energies were determined. Studies of the vaporization of solid ThOF/sub 2/ were started. Entropies and structures of UX/sub 4/ and ThX/sub 4/ (X = halide) are discussed. Sublimation of ThCl/sub 4/ and the vapor mass spectra were studied. (DLC)

Research Organization:
SRI International, Menlo Park, CA (USA)
DOE Contract Number:
AC03-85ER40237
OSTI ID:
6014757
Report Number(s):
DOE/ER/40237-T3; ON: DE88001564
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTINIDE COMPOUNDS
BROMIDES
BROMINE COMPOUNDS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
DECOMPOSITION
DISSOCIATION ENERGY
ENERGY
ENTROPY
EVAPORATION
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
MASS SPECTRA
MOLECULAR STRUCTURE
OXYFLUORIDES
OXYGEN COMPOUNDS
PHASE TRANSFORMATIONS
PHYSICAL PROPERTIES
RESEARCH PROGRAMS
SPECTRA
SUBLIMATION
THERMODYNAMIC PROPERTIES
THORIUM BROMIDES
THORIUM CHLORIDES
THORIUM COMPOUNDS
URANIUM COMPOUNDS