Synthetic metals based on tetramethyltetraselenafulvalene(TMTSF): synthesis, structure (T = 298 and 125 K), and novel properties of (TMTSF)/sub 2/H/sub 2/F/sub 3/

Journal Article · Fri Oct 01 04:00:00 EDT 1982 · Inorg. Chem.; (United States)

DOI:https://doi.org/10.1021/ic00140a059· OSTI ID:6012577

Beno, M A ^[1]; Blackman, G S; Williams, J M; Bechgaard, K

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1. Argonne National Lab., IL

The synthesis and molecular structure as a function of temperature (T = 298K and 125K) of the unique tetramethyltetraselenafulvalene organic radical cation salt (TMTSF)/sub 2/H/sub 2/F/sub 3/ is discussed in this report. The relationship between the structure and the unusual physical properties of (TMTSF)/sub 2/H/sub 2/F/sub 3/, and of its sometimes superconducting cogeners, is also discussed.

• DOE Contract Number: W-31109-ENG-38
• OSTI ID: 6012577
• Journal Information: Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 21:10; ISSN INOCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
CHEMICAL PREPARATION
CHEMICAL PROPERTIES
COMPLEXES
ELEMENTS
HYDROCARBONS
IRON
METALS
MOLECULAR STRUCTURE
ORGANIC COMPOUNDS
SELENIUM COMPLEXES
SYNTHESIS
TEMPERATURE EFFECTS
TRANSITION ELEMENTS