High-valent dioxoruthenium(VI) complex of 2,2'-bipyridine (bpy) - preparation and characterization of trans-(Ru/sup VI/(bpy)/sub 2/O/sub 2/)/sup 2 +/
Journal Article
·
· Inorg. Chem.; (United States)
The preparation and characterization of trans-(Ru/sup VI/(bpy)/sub 2/O/sub 2/)/sup 2 +/ (bpy = 2,2'-bipyridine) are described. The observed high E/sub f//sup 0/ value (1.25 V vs. NHE) for the trans-(Ru/sup VI/(bpy)/sub 2/O)/sub 2//sup 2 +//trans-(Ru/sup IV/(bpy)/sub 2/O(OH/sub 2/))/sup 2 +/ couple indicates that trans-(Ru/sup VI/(bpy)/sub 2/O/sub 2/)/sup 2 +/ is potentially useful for the photocatalytic splitting of water to oxygen. 10 references, 5 figures.
- Research Organization:
- Univ. of Hong Kong
- OSTI ID:
- 6012098
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 25:3; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Luminescence of ruthenium(II) tris chelate complexes containing the ligands 2,2'-bipyridine and 2,2'-biisoquinoline. Behavior of the Ru(bpy)/sup 2 +/ and Ru(bpy)/sub 2//sup 2 +/ emitting units
Proton-coupled electron-transfer reactions. Mechanisms of two-electron reduction of trans-dioxoruthenium(VI) to trans-aquooxoruthenium(VI) and disproportionation of trans-dioxoruthenium(V)
Concerning the absorption spectra of the ions M(bpy)/sub 3//sup 2 +/ (M = Fe, Ru, Os; bpy = 2,2'-bipyridine)
Journal Article
·
Tue Jan 15 23:00:00 EST 1985
· Inorg. Chem.; (United States)
·
OSTI ID:5738396
Proton-coupled electron-transfer reactions. Mechanisms of two-electron reduction of trans-dioxoruthenium(VI) to trans-aquooxoruthenium(VI) and disproportionation of trans-dioxoruthenium(V)
Journal Article
·
Wed Jun 20 00:00:00 EDT 1990
· Journal of the American Chemical Society; (USA)
·
OSTI ID:6620125
Concerning the absorption spectra of the ions M(bpy)/sub 3//sup 2 +/ (M = Fe, Ru, Os; bpy = 2,2'-bipyridine)
Journal Article
·
Sun Oct 31 23:00:00 EST 1982
· Inorg. Chem.; (United States)
·
OSTI ID:6387890
Related Subjects
08 HYDROGEN
080106 -- Hydrogen-- Production-- Biosynthesis & Photochemical Processes
14 SOLAR ENERGY
140505 -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400400 -- Electrochemistry
400500* -- Photochemistry
ABSORPTION SPECTROSCOPY
AZINES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DATA
ELECTROCHEMISTRY
ELEMENTS
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
HYDROGEN COMPOUNDS
INFORMATION
NONMETALS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN
OXYGEN COMPLEXES
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PYRIDINES
REACTION INTERMEDIATES
RUTHENIUM COMPLEXES
SPECTRA
SPECTROSCOPY
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
ULTRAVIOLET SPECTRA
VISIBLE SPECTRA
VOLTAMETRY
WATER
080106 -- Hydrogen-- Production-- Biosynthesis & Photochemical Processes
14 SOLAR ENERGY
140505 -- Solar Energy Conversion-- Photochemical
Photobiological
& Thermochemical Conversion-- (1980-)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400400 -- Electrochemistry
400500* -- Photochemistry
ABSORPTION SPECTROSCOPY
AZINES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL PREPARATION
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DATA
ELECTROCHEMISTRY
ELEMENTS
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
HYDROGEN COMPOUNDS
INFORMATION
NONMETALS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN
OXYGEN COMPLEXES
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PYRIDINES
REACTION INTERMEDIATES
RUTHENIUM COMPLEXES
SPECTRA
SPECTROSCOPY
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
ULTRAVIOLET SPECTRA
VISIBLE SPECTRA
VOLTAMETRY
WATER