Mercuration of alkylcyclopropanes with electron-accepting substituents in the aromatic ring

Journal Article · Sat Sep 10 00:00:00 EDT 1988 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6008538

Bandaev, S G; Eshnazarov, Yu K; Nasyrov, I M; Mochalov, S S; Shabarov, Yu S

The reactions of (nitrophenyl)- and (acetylphenyl)cyclopropanes with mercuric nitrate and acetate in methanol, acetic acid, and formic acid were studied. The arylcyclopropanes are mercurated by mercuric acetate in formic acid or by mercuric nitrate in all the employed solvents without a catalyst (perchloric acid). A relatively high rate of conjugate mercuration of arylcyclopropanes in formic acid was observed.

• Research Organization: M.V. Lomonosov Moscow State Univ. (USSR)
• OSTI ID: 6008538
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 24:4; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETATES
ACETIC ACID
ALCOHOLS
ALKALI METAL COMPOUNDS
ALKANES
AROMATICS
BINDING ENERGY
CARBOXYLIC ACID SALTS
CARBOXYLIC ACIDS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHLORIDES
CHLORINE COMPOUNDS
CHROMATOGRAPHY
CYCLOALKANES
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
FERMIONS
FORMIC ACID
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INFRARED SPECTRA
INORGANIC ACIDS
KINETICS
LEPTONS
MERCURY COMPOUNDS
MERCURY NITRATES
METHANOL
MONOCARBOXYLIC ACIDS
NITRATES
NITRO COMPOUNDS
NITROGEN COMPOUNDS
NMR SPECTRA
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC MERCURY COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PERCHLORIC ACID
REACTION KINETICS
SEPARATION PROCESSES
SODIUM CHLORIDES
SODIUM COMPOUNDS
SPECTRA
SYNTHESIS
THIN-LAYER CHROMATOGRAPHY
VALENCE