Some features of the oxidative conversion of Mo(CO)/sub 6/ in a medium of hydroperoxide or tert-butyl hydroperoxide and an aromatic hydrocarbon
Occurrence of the reaction under study was followed from the decrease in hydroperoxide or of Mo(CO)/sub 6/. The Mo(CO)/sub 6/ content of the reaction was found by determining either the concentration of this compound directly or by determining the concentration of the gaseous products from its transformations (CO + CO/sub 2/). Hydroperoxides (I) and (II) were determined iodometrically. Metal-containing products of the oxidation of Mo(CO)/sub 6/, molybdenum oxides and peroxides, were analyzed by IR and ESR spectroscopy, elemental analysis, and iodometry. Analysis of transformation products of the hydroperoxides (phenol, acetone, dimethylphenylcarbinol, acetophenone, tert-butyl alcohol, water, and oxygen) was performed using gas chromatography. Results are presented.
- Research Organization:
- N.I. Lobachevskii Gor'kii State Univ. (USSR)
- OSTI ID:
- 6007729
- Journal Information:
- J. Gen. Chem. USSR (Engl. Transl.); (United States), Vol. 57:9; Other Information: Translated from Zh. Obshch. Khim.; 57: No. 9, 2042-2049(Sep 1987)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBONYLS
OXIDATION
MOLYBDENUM COMPOUNDS
BENZENE
CHEMICAL REACTION KINETICS
DECOMPOSITION
ELECTRON SPIN RESONANCE
GAS CHROMATOGRAPHY
INFRARED SPECTRA
IODOMETRY
MOLYBDENUM COMPLEXES
MOLYBDENUM OXIDES
PEROXIDES
QUANTITY RATIO
STRUCTURAL CHEMICAL ANALYSIS
TOLUENE
XYLENE-PARA
ALKYLATED AROMATICS
AROMATICS
CHALCOGENIDES
CHEMICAL REACTIONS
CHROMATOGRAPHY
COMPLEXES
HYDROCARBONS
KINETICS
MAGNETIC RESONANCE
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
RESONANCE
SEPARATION PROCESSES
SPECTRA
TITRATION
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
XYLENES
400201* - Chemical & Physicochemical Properties