Kinetics of individual and joint hydrocarbon oxidation

Journal Article · Wed Oct 20 00:00:00 EDT 1982 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00950013· OSTI ID:6000401

Dryakhlov, A S; Ulybin, B E; Kalinkina, L I; Kisarov, V M; Beskov, V S; Kiperman, S L

This report investigated the deep oxidation of mixtures of saturated hydrocarbons which differ in their oxidation mechanisms. Binary mixtures of n-pentane and p-xylene and cyclohexane and p-xylene, and tertiary mixtures of n-pentane, cyclohexane and p-xylene were used in this study. The work carried out here has shown the possibility of constructing kinetic models for the oxidation of mixtures of organic compounds from individual compound oxidation models, involving different adsorptional competition mechanisms. Data was obtained on the kinetics of the joint, deep oxidation of n-pentane, cyclohexane, and p-xylene on an aluminum/platinum catalyst in a circulating-flow reactor. The oxidation of each of these compounds can be described by a single equation.

• Research Organization: Academy of Sciences of the USSR, Moscow
• OSTI ID: 6000401
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 31:4; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKANES
AROMATICS
CHEMICAL ANALYSIS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CYCLOALKANES
CYCLOHEXANE
HYDROCARBONS
KINETICS
ORGANIC COMPOUNDS
OXIDATION
PENTANE
QUANTITATIVE CHEMICAL ANALYSIS
REACTION KINETICS
XYLENES