Studies on the metal poisoning and metal resistance of zeolitic cracking catalysts

Journal Article · Fri May 01 00:00:00 EDT 1987 · Ind. Eng. Chem. Res.; (United States)

DOI:https://doi.org/10.1021/ie00065a001· OSTI ID:5997184

Chester, A W

The effects of metal poisons (Ni, V) on zeolitic cracking catalyst have been investigated with the goal of developing a method for determining the inherent metal resistance of different catalyst compositions in the laboratory. Metal resistance is evaluated by determining activity and selectivity both before and after a synthetic poisoning procedure so that ''contaminant yields'' - the excess coke and hydrogen produced by metals during cracking - could be calculated. After several methods are compared, that chosen involves impregnation of steam-deactivated catalysts with a gas oil doped with metal naphthenates, followed by high-temperature cracking and regeneration.

• Research Organization: Paulsboro Research Lab., Mobil Research and Development Corp., Paulsboro, NJ 08066
• OSTI ID: 5997184
• Journal Information: Ind. Eng. Chem. Res.; (United States), Journal Name: Ind. Eng. Chem. Res.; (United States) Vol. 26:5; ISSN IECRE
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
020400* -- Petroleum-- Processing
ACTIVATION ENERGY
ALKANES
BENCH-SCALE EXPERIMENTS
CALCULATION METHODS
CATALYTIC CRACKING
CATALYTIC EFFECTS
CHEMICAL COMPOSITION
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
COKE
COMPARATIVE EVALUATIONS
CRACKING
CYCLOALKANES
DEACTIVATION
DECOMPOSITION
ELEMENTS
ENERGY
ENERGY SOURCES
FOSSIL FUELS
FUELS
GAS OILS
HYDROCARBONS
HYDROGEN PRODUCTION
IMPURITIES
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
MATERIALS
METALS
MINERALS
NICKEL
ORGANIC COMPOUNDS
PETROLEUM
PETROLEUM FRACTIONS
PETROLEUM PRODUCTS
PYROLYSIS
REGENERATION
STEAM
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENTS
VANADIUM
YIELDS
ZEOLITES