Micellar radical pair decay
Journal Article
·
· Journal of Chemical Physics; (USA)
- Beckman Institute University of Illinois,Urbana-Champaign, IL (USA) Department of Physics, University of Illinois,Urbana-Champaign, IL (USA)
- Department ofChemistry, Columbia University, New York, NY (USA)
The magnetic-field dependence of hyperfine coupling-induced radical pair processes in micelles is studied theoretically. We show that experimental observations on reaction dynamics of triplet benzylic radical pairs can be explained by a hyperfine interaction mechanism when the exchange interaction between the unpaired spins in the radical pair confined to a micelle is taken into account. The theoretical description applied involves a stochastic Liouville equation. The time-dependent solutions of the stochastic Liouville equation qualitatively reproduce the observed magnetic-field and isotope dependence of micellar radical pair decay.
- OSTI ID:
- 5995581
- Journal Information:
- Journal of Chemical Physics; (USA), Journal Name: Journal of Chemical Physics; (USA) Vol. 93:11; ISSN JCPSA; ISSN 0021-9606
- Country of Publication:
- United States
- Language:
- English
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