Equilibrium sorption of cobalt, cesium and strontium on Bandelier Tuff: analysis of alternative mathematical modeling
Sorption isotherms are derived from batch equilibrium data for cobalt, cesium and strontium on Bandelier Tuff. Experiments were conducted at an average temperature of 23{sup 0}C and equilibrium was defined at 48 hours. The solute concentrations ranged from 0 to 500 mg/L. The radioactive isotopes {sup 60}Co, {sup 137}Cs, and {sup 85}Sr were used to trace the sorption of the stable solutes. The Linear, Langmuir, Freundlich and a Modified Freundlich isotherm equations are evaluated. The Modified Freundlich isotherm equation is validated as a preferred general mathematical tool for representing the sorption of the three solutes. The empirical constants derived from the Modified Freundlich isotherm equation indicate that under dynamic flow conditions strontium will move most rapidly and cobalt least rapidly. On the other hand, chemical dispersion will be greatest for cesium and least for strontium. Hill Plots of the sorption data suggest that in the region of low saturation sorption of all three solutes is impeded by interactions among sorption sites; cobalt exhibits the greatest effect of interactions and strontium shows only a minimal effect. In the saturation region of 50% or more, sorption of cobalt is enhanced slightly by interactions among sorption sites whereas sorption of cesium and strontium appears to be independent of site interactions.
- Research Organization:
- Arizona Univ., Tucson, AZ (United States). Coll. of Engineering; Los Alamos National Lab., NM
- OSTI ID:
- 59928
- Report Number(s):
- CONF-850314--Vol.3; ON: TI86006918
- Country of Publication:
- United States
- Language:
- English
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54 ENVIRONMENTAL SCIENCES
58 GEOSCIENCES
CESIUM
CESIUM 137
COBALT
COBALT 60
DYNAMIC FUNCTION STUDIES
EQUILIBRIUM
HILL EQUATION
ISOTHERMS
LEACHING
LINEAR ABSORPTION MODELS
QUANTITY RATIO
RADIOACTIVE WASTE DISPOSAL
RADIONUCLIDE MIGRATION
SOLUTES
SORPTION
STRONTIUM
STRONTIUM 85
TUFF
WASTE-ROCK INTERACTIONS
Yucca Mountain Project