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Deuterium fractionation mechanisms in interstellar clouds

Journal Article · · Astrophys. J., Lett. Ed.; (United States)
DOI:https://doi.org/10.1086/184395· OSTI ID:5992633
The theory of the fractionation of deuterated molecules is extended to include reactions with atomic deuterium. With the recognition that dissociative recombination of H/sup +//sub 3/ is not rapid, observational data can be used in conjunction with the theory to derive upper and lower bounds to the cosmic deuterium-hydrogen abundance ratio. We find that (D)/(H) is at least 3.4 x 10/sup -6/ and at most 4.0 x 10/sup -5/ with a probable value of 1 x 10/sup -5/. Because of the reaction HCO/sup +/+D..-->..DCO/sup +/+H, upper limits can be derived for the fractional ionization which depend only weakly on the cosmic ray flux, zeta. In four clouds, the upper limits to the fractional ionization lie between 1.1 x 10/sup -6/ and 1.5 x 10/sup -6/ if zeta = 10/sup -7/ s/sup -1/ and between 3.1 x 10/sup -6/ and 1.8 x 10/sup -6/ if zeta = 10/sup -16/ s/sup -1/.
Research Organization:
Harvard-Smithsonian Center for Astrophysics
OSTI ID:
5992633
Journal Information:
Astrophys. J., Lett. Ed.; (United States), Journal Name: Astrophys. J., Lett. Ed.; (United States) Vol. 287:1; ISSN AJLEA
Country of Publication:
United States
Language:
English