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Environmental embrittlement of ordered intermetallic alloys at room temperature in moist atmospheres

Conference ·
OSTI ID:5981112
This paper provides a comprehensive review of recent research on environmental embrittlement of ordered intermetallic alloys at ambient temperatures. Ordered intermetallics containing reactive elements such as Al, Si, Ti and V exhibit a severe reduction in ductility when tested in moisture-containing environments (e.g., moist air), instead of dry environments. The embrittlement involves the reaction of the reactive elements with moisture in air and generation of atomic hydrogen at crack tips. The loss in ductility is generally accompanied by a change in fracture mode from ductile rupture to brittle grain-boundary fracture in fcc-ordered intermetallics, and to brittle cleavage in bcc-ordered intermetallics. The underlying mechanisms of the hydrogen embrittlement are also discussed in this paper. 55 refs., 4 figs., 5 tabs.
Research Organization:
Oak Ridge National Lab., TN (USA)
Sponsoring Organization:
DOE; USDOE, Washington, DC (USA)
DOE Contract Number:
AC05-84OR21400
OSTI ID:
5981112
Report Number(s):
CONF-9106146-5; ON: DE91012051
Country of Publication:
United States
Language:
English