Solid phase spectrophotometric microdetermination of copper

Journal Article · Mon Jul 01 04:00:00 EDT 1991 · Analytical Letters; (United States)

DOI:https://doi.org/10.1080/00032719108052964· OSTI ID:5977639

Capitan, F; Roman Navarro, J M; Capitan-Vallvey, L F ^[1]

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1. Univ. of Granada (Spain)

A method for the determination of microgram per liter level of copper has been developed, based on Solid-Phase Spectrophotometry (SPS). Copper reacts with bichinconinic acid to form a 1:2 anionic reddish purple of complex Cu(I), which is fixed on a dextran-type anion-exchange resin. Resin phase absorbance is measured directly and allows for the determination of copper within the range of 1-20 {mu}g.1{sup {minus}1}, using a 2,000 ml sample with an RSD of 1.7%. The method has been used in the determination of copper in natural waters.

• OSTI ID: 5977639
• Journal Information: Analytical Letters; (United States), Journal Name: Analytical Letters; (United States) Vol. 24:7; ISSN ANALB; ISSN 0003-2719
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400102* -- Chemical & Spectral Procedures
54 ENVIRONMENTAL SCIENCES
540320 -- Environment
Aquatic-- Chemicals Monitoring & Transport-- (1990-)
ABSORPTION SPECTROSCOPY
ANIONS
AROMATICS
AZAARENES
AZINES
BUFFERS
CALIBRATION
CHARGED PARTICLES
CHEMICAL ANALYSIS
CHROMATOGRAPHY
COMPLEXES
COPPER
COPPER COMPLEXES
DATA
DRINKING WATER
ELEMENTS
EXPERIMENTAL DATA
FRESH WATER
HETEROCYCLIC COMPOUNDS
HYDROGEN COMPOUNDS
INFORMATION
ION EXCHANGE CHROMATOGRAPHY
IONS
METALS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PH VALUE
PYRIDINES
QUANTITATIVE CHEMICAL ANALYSIS
QUINOLINES
SAMPLE PREPARATION
SEPARATION PROCESSES
SPECTROSCOPY
STOICHIOMETRY
TRACE AMOUNTS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENTS
WATER