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Acylamidation of acetylenes

Journal Article · · J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:5971937
;
The reactions of phenylacetylene, 1-heptyne, and diphenylacetylene with the complexes of acetylfluoroborate with acetonitrile and with chloroacetonitrile take place regiospecifically and stereospecifically as syn-addition of the acetyl group and nitrile at the triple bond of the acetylene and lead to previously unknown Z-N-acyl-/beta/-amino, /alpha/,/beta/-unsaturated ketones.
OSTI ID:
5971937
Journal Information:
J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 24:8; ISSN JOCYA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETONITRILE
ACTIVATION ENERGY
ACYLATION
ALKYNES
AMINES
BORON COMPOUNDS
CARBON 13
CARBON ISOTOPES
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
ENERGY
EVEN-ODD NUCLEI
FLUORINE COMPOUNDS
FLUOROBORATES
HALOGEN COMPOUNDS
HYDROCARBONS
ISOTOPES
KETONES
KINETICS
LIGHT NUCLEI
NITRILES
NMR SPECTRA
NUCLEI
ORGANIC BORON COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
REACTION KINETICS
SPECTRA
STABLE ISOTOPES
STEREOCHEMISTRY
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
YIELDS