Stereochemistry of the epoxidation of internal perfluoroalkenes with sodium hypochlorite

Journal Article · Wed Jul 20 04:00:00 EDT 1988 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5971341

Filyakova, T I; Peschanskii, N V; Kodess, M I; Zapevalov, A Ya; Kolenko, I P

The authors studied the epoxidation of the mixture of cis and trans isomers of internal disubstituted perfluoroalkenes with sodium hypochlorite. Epoxidation was realized with an alkaline aqueous solution of sodium hypochlorite in the presence of acetonitrile. The epoxidation of the geometric isomers of internal disubstituted perfluoroalkenes by sodium hypochlorite is stereospecific. The /sup 19/F NMR spectra of the cis and trans isomers of internal perfluoroolefin oxides were obtained, and the relationships are discussed.

• Research Organization: Institute of Chemistry, Sverdlovsk (USSR)
• OSTI ID: 5971341
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 24:2; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPOUNDS
ALKANES
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORINE COMPOUNDS
COUPLING
COUPLING CONSTANTS
DOUBLE RESONANCE METHODS
EPOXIDES
FLUORINATED ALIPHATIC HYDROCARBONS
FLUORINE 19
FLUORINE ISOTOPES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
INTERMEDIATE COUPLING
ISOMERIZATION
ISOMERS
ISOTOPES
J-J COUPLING
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXYCHLORIDES
OXYGEN COMPOUNDS
SODIUM COMPOUNDS
SPECTRA
STABLE ISOTOPES
STEREOCHEMISTRY
STRUCTURAL CHEMICAL ANALYSIS
YIELDS