Preparation of dinitrogen, hydrido, and carbonyl complexes of molybdenum and tungsten from higher halides
Journal Article
·
· J. Gen. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:5970901
The yields, physicochemical properties, and analyses of phosphine complexes of molybdenum and tungsten are shown. The reduction of molydenum pentachloride or tungsten hexachloride with metallic magnesium in THF in the presence of a tertiary organic phosphines in an atmosphere of nitrogen, hydrogen, or carbon monoxide provided a convenient method for the preparation of dinitrogen M(N/sub 2/)/sub 2/L/sub 4/, hydride MH/sub 4/L/sub 4/, or carbonyl M(CO)/sub 6/minus/x/L/sub x/ complexes respectively of molybdenum or tungsten (M = Mo, W; L - tertiary organic phosphine).
- Research Organization:
- Institute of New Chemical Problems, Chernogolovka (USSR)
- OSTI ID:
- 5970901
- Journal Information:
- J. Gen. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Gen. Chem. USSR (Engl. Transl.); (United States) Vol. 57:8; ISSN JGCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CARBONYLS
CHEMICAL REACTION YIELD
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
FURANS
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
INFRARED SPECTRA
LIGANDS
MOLYBDENUM CHLORIDES
MOLYBDENUM COMPLEXES
MOLYBDENUM COMPOUNDS
MOLYBDENUM HYDRIDES
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
PHOSPHINES
PHOSPHORUS COMPOUNDS
REFRACTORY METAL COMPOUNDS
SPECTRA
SPECTROPHOTOMETRY
SYNTHESIS
TETRAHYDROFURAN
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN CHLORIDES
TUNGSTEN COMPLEXES
TUNGSTEN COMPOUNDS
TUNGSTEN HYDRIDES
YIELDS
400201* -- Chemical & Physicochemical Properties
CARBONYLS
CHEMICAL REACTION YIELD
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
FURANS
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HYDRIDES
HYDROGEN COMPOUNDS
INFRARED SPECTRA
LIGANDS
MOLYBDENUM CHLORIDES
MOLYBDENUM COMPLEXES
MOLYBDENUM COMPOUNDS
MOLYBDENUM HYDRIDES
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
PHOSPHINES
PHOSPHORUS COMPOUNDS
REFRACTORY METAL COMPOUNDS
SPECTRA
SPECTROPHOTOMETRY
SYNTHESIS
TETRAHYDROFURAN
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN CHLORIDES
TUNGSTEN COMPLEXES
TUNGSTEN COMPOUNDS
TUNGSTEN HYDRIDES
YIELDS