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Experimental investigation of atmospheric pressure nonequilibrium plasma chemistry

Journal Article · · IEEE Transactions on Plasma Science
DOI:https://doi.org/10.1109/27.649624· OSTI ID:596827

Atmospheric pressure plasmas are frequently considered to be in local thermodynamic equilibrium due to the high frequency of collisional processes which drive the plasma state toward a Maxwell-Boltzmann equilibrium. However, various forms of thermodynamic, ionizational, and chemical nonequilibrium have been demonstrated and investigated in atmospheric pressure plasma environments over the last several years, and the nonequilibrium behavior of such systems can be quite significant. The investigation, understanding, and exploitation of atmospheric pressure nonequilibrium plasma chemistry is necessary to the further expansion of plasma-based systems into mainstream manufacturing and processing applications. Several experimental programs to investigate the fundamental processes of atmospheric pressure nonequilibrium plasma chemistry and the application of this nonequilibrium to various chemical systems have been undertaken in the authors` laboratories. The results of these investigations have shed light on the kinetics behind various forms of atmospheric pressure nonequilibrium chemistry, and have provided insights into the beneficial control of nonequilibrium plasma chemistry for processing applications.

Sponsoring Organization:
USDOE, Washington, DC (United States); Department of the Air Force, Washington, DC (United States); Electric Power Research Inst., Palo Alto, CA (United States)
DOE Contract Number:
FG03-88ER13957
OSTI ID:
596827
Journal Information:
IEEE Transactions on Plasma Science, Journal Name: IEEE Transactions on Plasma Science Journal Issue: 5 Vol. 25; ISSN ITPSBD; ISSN 0093-3813
Country of Publication:
United States
Language:
English

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