Theory of corrosion of alkali-borosilicate glass

Conference · Sat Jan 01 04:00:00 EST 1983 · Mater. Res. Soc. Symp. Proc.; (United States)

OSTI ID:5961174

Clark, D E; Hench, L L

The alkali-borosilicate (ABS) system provides the basis for a wide variety of commercially important products among which are the nuclear waste glasses. Although a large number of investigations have been undertaken in the last five years, the corrosion mechanisms of the ABS glasses have not been characterized nearly as well as for the soda-lime-silicate (NCS) glasses commonly used for containers. It is well known that the corrosion of the latter glasses involves ion exchange, network dissolution, and precipitation mechanisms resulting in the development of one of five types of surface films. In the present paper we compare the corrosion behavior to the ABS and NCS glasses and discuss our current understanding of ABS glass corrosion in terms of mechanisms, kinetics, surface film formation and thermodynamics.

• Research Organization: Univ. of Florida, Gainesville
• OSTI ID: 5961174
• Report Number(s): CONF-821107-Pt.1
• Conference Information: Journal Name: Mater. Res. Soc. Symp. Proc.; (United States) Journal Volume: 15
• Country of Publication: United States
• Language: English

Related Subjects

052002 -- Nuclear Fuels-- Waste Disposal & Storage
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES
36 MATERIALS SCIENCE
360604* -- Materials-- Corrosion
Erosion
& Degradation
BOROSILICATE GLASS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CORROSION
DISSOLUTION
GLASS
ION EXCHANGE
KINETICS
LEACHING
REACTION KINETICS
SEPARATION PROCESSES