Study of a glass-forming area in the Tl/sub 2/S-Sb/sub 2/S/sub 3/ system; structural investigation by /sup 121/Sb Mossbauer spectroscopy
Journal Article
·
· J. Solid State Chem.; (United States)
OSTI ID:5953837
The study of a glass-forming area in the Tl/sub 2/S-Sb/sub 2/S/sub 3/ system was determined (from 0.6 to 0.95 expressed in molar ratio of Sb/sub 2/S/sub 3/). These glasses were then characterized by measuring their glass transition temperature. T /SUB g/ , and by electron microscopy and powder X-ray diffraction. The glass-forming are and its limits are discussed in terms of structural investigation by /sup 121/Sb Mossbauer spectroscopy in connection with the results of corresponding crystallized compounds and their optical transparency
- Research Organization:
- Laboratoire de Physico-Chimie des Materiaux U.A. 407, Universite des Sciences et Techniques du Languedoc, Place Eugene Bataillon, Montpellier
- OSTI ID:
- 5953837
- Journal Information:
- J. Solid State Chem.; (United States), Journal Name: J. Solid State Chem.; (United States) Vol. 59:2; ISSN JSSCB
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
360601* -- Other Materials-- Preparation & Manufacture
360602 -- Other Materials-- Structure & Phase Studies
ANTIMONY 121
ANTIMONY COMPOUNDS
ANTIMONY ISOTOPES
ANTIMONY SULFIDES
CHALCOGENIDES
CHEMICAL COMPOSITION
CHEMICAL PREPARATION
COHERENT SCATTERING
CRYSTAL-PHASE TRANSFORMATIONS
CRYSTALLIZATION
CRYSTALLOGRAPHY
DIFFRACTION
ELECTRON MICROSCOPY
GLASS
INTERMEDIATE MASS NUCLEI
ISOTOPES
MICROSCOPY
MOESSBAUER EFFECT
NUCLEI
ODD-EVEN NUCLEI
OPACITY
OPTICAL PROPERTIES
PHASE TRANSFORMATIONS
PHYSICAL PROPERTIES
SCATTERING
SPECTROSCOPY
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
SULFIDES
SULFUR COMPOUNDS
SYNTHESIS
TEMPERATURE MEASUREMENT
THALLIUM COMPOUNDS
THALLIUM SULFIDES
THERMODYNAMIC PROPERTIES
TRANSITION TEMPERATURE
X-RAY DIFFRACTION
360601* -- Other Materials-- Preparation & Manufacture
360602 -- Other Materials-- Structure & Phase Studies
ANTIMONY 121
ANTIMONY COMPOUNDS
ANTIMONY ISOTOPES
ANTIMONY SULFIDES
CHALCOGENIDES
CHEMICAL COMPOSITION
CHEMICAL PREPARATION
COHERENT SCATTERING
CRYSTAL-PHASE TRANSFORMATIONS
CRYSTALLIZATION
CRYSTALLOGRAPHY
DIFFRACTION
ELECTRON MICROSCOPY
GLASS
INTERMEDIATE MASS NUCLEI
ISOTOPES
MICROSCOPY
MOESSBAUER EFFECT
NUCLEI
ODD-EVEN NUCLEI
OPACITY
OPTICAL PROPERTIES
PHASE TRANSFORMATIONS
PHYSICAL PROPERTIES
SCATTERING
SPECTROSCOPY
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
SULFIDES
SULFUR COMPOUNDS
SYNTHESIS
TEMPERATURE MEASUREMENT
THALLIUM COMPOUNDS
THALLIUM SULFIDES
THERMODYNAMIC PROPERTIES
TRANSITION TEMPERATURE
X-RAY DIFFRACTION