Inhibition of the epoxidation of olefins by organic hydroperoxides

Journal Article · Sat Dec 31 23:00:00 EST 1988 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:5950674

Vedenev, V N; Mel'nik, L V; Bobylev, B N

The inhibition of the epoxidation of olefins by organic hydroperoxides, produced by products of this synthesis, was studied. A method is proposed for estimating the relative instability constants of the catalyst-inhibitor complex. It was shown that the effect of inhibition of the epoxidation reaction increases in the following series of compounds: epoxides < epoxyolefins < C/sub 1/ - C/sub 4/ alcohols < diepoxides < diols /approx equal/ unsaturated diols /much lt/ tetrols.

• Research Organization: Yaroslavl Polytechnic Institute (USSR)
• OSTI ID: 5950674
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 29:4; ISSN KICAA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical &amp; Physicochemical Properties
ACTIVATION ENERGY
ALCOHOLS
ALKENES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
ENERGY
EPOXIDES
HYDROCARBONS
HYDROXY COMPOUNDS
INFRARED SPECTRA
INHIBITION
KINETICS
MATHEMATICAL MODELS
MOLYBDENUM COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC POLYMERS
OXYGEN COMPOUNDS
PEROXIDES
PETROCHEMICALS
PETROLEUM PRODUCTS
POLYMERS
QUANTITY RATIO
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
RESINS
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
TRANSITION ELEMENT COMPOUNDS
YIELDS