Direct synthesis of dipropyl- and diisopropylzinc

Journal Article · Sun Mar 20 04:00:00 EST 1988 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:5949457

Pochekutova, T S; Khamylov, V K; Domrachev, G A; Zhuk, B V

The synthesis of dipropyl- and diisopropylzinc in the reaction of propyl and isopropyl iodide with zinc and a zinc-iron mixture at the gas-solid boundary in a flow-type system was studied. It was shown that the reaction leads to synthesis of the dialkylzinc or dissociation of the dialkylzinc and alkyl iodide, depending on the process temperature. During the reaction of propyl iodide with zinc or the zinc-iron mixture the propyl radical undergoes isomerization within the complex and diisopropylzinc is formed.

• OSTI ID: 5949457
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 23:10; ISSN JOCYA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKANES
BOUNDARY LAYERS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHROMATOGRAPHY
COMPLEXES
COMPLEXOMETRY
DECOMPOSITION
DISSOCIATION
ELEMENTS
FLUIDS
GASES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDRIODIC ACID
HYDROCARBONS
HYDROGEN COMPOUNDS
INORGANIC ACIDS
IODINATED ALIPHATIC HYDROCARBONS
IODINE COMPOUNDS
IRON
ISOMERIZATION
KINETICS
LAYERS
METALS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANOMETALLIC COMPOUNDS
POWDERS
PROPANE
PYROLYSIS
RADICALS
REACTION KINETICS
SEPARATION PROCESSES
SYNTHESIS
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENTS
VAPORS
YIELDS
ZINC
ZINC COMPLEXES