Electronic structure and properties of unsubstituted rhodamine in different electron states
Journal Article
·
· Sov. Phys. J. (Engl. Transl.); (United States)
OSTI ID:5946827
An analysis is given of the electron density distribution, dipole moment variation, and proton acceptor properties of unsubstituted rhodamine molecules in different electron states. It is shown that the electron density redistribution between the pyronine and benzoin parts of rhodamine may be large and strongly affect the molecular properties. In one of the electron transitions (S/sub 4/) producing the third absorption band the proton acceptor power markedly increases, giving rise to a protonated form under suitable conditions.
- Research Organization:
- Tomsk State Univ. (USSR)
- OSTI ID:
- 5946827
- Journal Information:
- Sov. Phys. J. (Engl. Transl.); (United States), Vol. 30:10; Other Information: Translated from Izv. Vyssh. Uchebn. Zaved., Fiz.; 30: No. 10, 50-53(Oct 1987)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
42 ENGINEERING
DYE LASERS
MATERIALS TESTING
RHODAMINES
ELECTRONIC STRUCTURE
ABSORPTION SPECTRA
CHARGE DISTRIBUTION
DIPOLE MOMENTS
EFFECTIVE CHARGE
ELECTRON DENSITY
EXCITATION
EXCITED STATES
GROUND STATES
LASER MATERIALS
OSCILLATOR STRENGTHS
AMINES
CARBOXYLIC ACIDS
DYES
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
LASERS
LIQUID LASERS
MATERIALS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
REAGENTS
SPECTRA
TESTING
420300* - Engineering- Lasers- (-1989)
DYE LASERS
MATERIALS TESTING
RHODAMINES
ELECTRONIC STRUCTURE
ABSORPTION SPECTRA
CHARGE DISTRIBUTION
DIPOLE MOMENTS
EFFECTIVE CHARGE
ELECTRON DENSITY
EXCITATION
EXCITED STATES
GROUND STATES
LASER MATERIALS
OSCILLATOR STRENGTHS
AMINES
CARBOXYLIC ACIDS
DYES
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
LASERS
LIQUID LASERS
MATERIALS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
REAGENTS
SPECTRA
TESTING
420300* - Engineering- Lasers- (-1989)