Some effects of sulfiding of a NiMo/Al/sub 2/O/sub 3/ catalyst on its activity for hydrodenitrogenation of quinoline

Journal Article · Sun May 01 00:00:00 EDT 1983 · J. Catal.; (United States)

OSTI ID:5944516

Yang, S H; Satterfield, C N

The method of presulfiding of a commercial nickel molybdenum/alumina (NiMo/Al/sub 2/O/sub 3/) catalyst has a significant effect on its inherent activity for the hydrodenitrogenation (HDN) or quinoline. In addition, during reaction the addition of nitrogen sulfide increases on the kinetics of a variety of hydrodenitrogenation, hydrodesulfurization, and hydrogenation reactions on molybdenum catalysts can be rationalized in terms of its effect on two kinds of sites, sulfur anion vacancies and Broensted acids. 7 figures, 1 table.

• Research Organization: Massachusetts Inst. of Technology, Cambridge
• DOE Contract Number: AC22-80PC30075
• OSTI ID: 5944516
• Journal Information: J. Catal.; (United States), Journal Name: J. Catal.; (United States) Vol. 81:1; ISSN JCTLA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
AZINES
BINARY MIXTURES
CATALYST SUPPORTS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL ANALYSIS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DATA
DENITRIFICATION
DISPERSIONS
ELEMENTS
EXPERIMENTAL DATA
HETEROCYCLIC COMPOUNDS
HIGH TEMPERATURE
HYDROGEN
HYDROGEN COMPOUNDS
HYDROGEN SULFIDES
HYDROGENATION
INFORMATION
KINETICS
MEDIUM PRESSURE
MEDIUM TEMPERATURE
METALS
MIXTURES
MOLYBDENUM
NICKEL
NONMETALS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PRESSURE DEPENDENCE
PYRIDINES
QUANTITATIVE CHEMICAL ANALYSIS
QUINOLINES
REACTION KINETICS
SULFIDATION
SULFIDES
SULFUR COMPOUNDS
TEMPERATURE DEPENDENCE
TRANSITION ELEMENTS