An unsymmetrical binuclear ruthenium(II) complex of tris(2-pyridyl)-1,3,5-triazine and its identification by sup 1 H NMR spectroscopy
Journal Article
·
· Inorganic Chemistry; (United States)
- Univ. of Houston, TX (United States)
The use of tris(2-pyridyl)-1,3,5-triazine (TPT) for use as a bridging ligand that incorporates two Ru(II) atoms in nonequivalent sites such that one Ru(II) is bound in a bidentate fashion and the other is bound in a tridentate manner is described herein. The use of bpy-d{sub 8} as an auxiliary ligand in the formation and characterization of an unsymmetrical mononuclear ruthenium (I) complex has been extended to the perdeuterio analog of 2,2{prime};6,2{double prime}-terpyridine (Tpy), and its use in the characterization of a binuclear complex of TPT are reported. {sup 1}H NMR chemical shift data for the ligands and the ruthenium complexes are presented. 15 refs., 3 figs., 1 tab.
- OSTI ID:
- 5943381
- Journal Information:
- Inorganic Chemistry; (United States), Vol. 30:13; ISSN 0020-1669
- Country of Publication:
- United States
- Language:
- English
Similar Records
Zero-order and first-derivative spectrophotometric determination of trace amounts of ruthenium after extraction of its ion association complex with 2,4,6-tris(2 prime -pyridyl)-1,3,5-triazine and picrate
Synthesis and characterization of rhodium complexes containing 2,4,6-tris(2-pyridyl)-1,3,5-triazine and its metal-promoted hydrolytic products: Potential uses of the new complexes in electrocatalytic reduction of carbon dioxide
Dipyrido[4,3-b;5,6-b]acridine derivatives and their ruthenium(II) complexes
Journal Article
·
Wed Jan 01 00:00:00 EST 1992
· Analytical Letters; (United States)
·
OSTI ID:5943381
+1 more
Synthesis and characterization of rhodium complexes containing 2,4,6-tris(2-pyridyl)-1,3,5-triazine and its metal-promoted hydrolytic products: Potential uses of the new complexes in electrocatalytic reduction of carbon dioxide
Journal Article
·
Mon Nov 02 00:00:00 EST 1998
· Inorganic Chemistry
·
OSTI ID:5943381
+3 more
Dipyrido[4,3-b;5,6-b]acridine derivatives and their ruthenium(II) complexes
Journal Article
·
Wed Sep 25 00:00:00 EDT 1996
· Inorganic Chemistry
·
OSTI ID:5943381
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
PYRIDINES
CHEMICAL PREPARATION
MOLECULAR STRUCTURE
RUTHENIUM COMPLEXES
TRIAZINES
CHEMICAL BONDS
DEUTERIUM
EXPERIMENTAL DATA
ISOTOPE EFFECTS
NMR SPECTRA
PROTONS
AZINES
BARYONS
COMPLEXES
DATA
ELEMENTARY PARTICLES
FERMIONS
HADRONS
HETEROCYCLIC COMPOUNDS
HYDROGEN ISOTOPES
INFORMATION
ISOTOPES
LIGHT NUCLEI
NUCLEI
NUCLEONS
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
PYRIDINES
CHEMICAL PREPARATION
MOLECULAR STRUCTURE
RUTHENIUM COMPLEXES
TRIAZINES
CHEMICAL BONDS
DEUTERIUM
EXPERIMENTAL DATA
ISOTOPE EFFECTS
NMR SPECTRA
PROTONS
AZINES
BARYONS
COMPLEXES
DATA
ELEMENTARY PARTICLES
FERMIONS
HADRONS
HETEROCYCLIC COMPOUNDS
HYDROGEN ISOTOPES
INFORMATION
ISOTOPES
LIGHT NUCLEI
NUCLEI
NUCLEONS
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties