An unsymmetrical binuclear ruthenium(II) complex of tris(2-pyridyl)-1,3,5-triazine and its identification by sup 1 H NMR spectroscopy
Journal Article
·
· Inorganic Chemistry; (United States)
- Univ. of Houston, TX (United States)
The use of tris(2-pyridyl)-1,3,5-triazine (TPT) for use as a bridging ligand that incorporates two Ru(II) atoms in nonequivalent sites such that one Ru(II) is bound in a bidentate fashion and the other is bound in a tridentate manner is described herein. The use of bpy-d{sub 8} as an auxiliary ligand in the formation and characterization of an unsymmetrical mononuclear ruthenium (I) complex has been extended to the perdeuterio analog of 2,2{prime};6,2{double prime}-terpyridine (Tpy), and its use in the characterization of a binuclear complex of TPT are reported. {sup 1}H NMR chemical shift data for the ligands and the ruthenium complexes are presented. 15 refs., 3 figs., 1 tab.
- OSTI ID:
- 5943381
- Journal Information:
- Inorganic Chemistry; (United States), Journal Name: Inorganic Chemistry; (United States) Vol. 30:13; ISSN 0020-1669; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AZINES
BARYONS
CHEMICAL BONDS
CHEMICAL PREPARATION
COMPLEXES
DATA
DEUTERIUM
ELEMENTARY PARTICLES
EXPERIMENTAL DATA
FERMIONS
HADRONS
HETEROCYCLIC COMPOUNDS
HYDROGEN ISOTOPES
INFORMATION
ISOTOPE EFFECTS
ISOTOPES
LIGHT NUCLEI
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
NUCLEONS
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PROTONS
PYRIDINES
RUTHENIUM COMPLEXES
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
TRIAZINES
400201* -- Chemical & Physicochemical Properties
AZINES
BARYONS
CHEMICAL BONDS
CHEMICAL PREPARATION
COMPLEXES
DATA
DEUTERIUM
ELEMENTARY PARTICLES
EXPERIMENTAL DATA
FERMIONS
HADRONS
HETEROCYCLIC COMPOUNDS
HYDROGEN ISOTOPES
INFORMATION
ISOTOPE EFFECTS
ISOTOPES
LIGHT NUCLEI
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
NUCLEONS
NUMERICAL DATA
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PROTONS
PYRIDINES
RUTHENIUM COMPLEXES
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
TRIAZINES