Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Electrochemical properties of the solvent SbCl/sub 3/-AlCl/sub 3/-N-(1-Butyl)Pyridinium chloride and electrochemical and spectroelectrochemical studies of arene solutes

Journal Article · · J. Electrochem. Soc.; (United States)
DOI:https://doi.org/10.1149/1.2115918· OSTI ID:5940803
; ; ; ;
Physical and electrochemical properties are reported for SbCl/sub 3/-AlCl/sub 3/-N-(1-butyl)pyridinium chloride (BPCl) mixtures that are liquid at ambient temperatures; and studies of the electrogeneration and open-circuit decay of some arene radical cations, both in this medium and in SbCl/sub 3/-KCl at elevated temperatures, are described. Specific conductivities, densities, and viscosities of various compositions of SbCl/sub 3/-AlCl/sub 3/-BPCl were measured over the temperature range 24-100/sup 0/C. For a potentiometric titration between the compositions 60:18:22 and 60:22:18 with SbCl/sub 3/ fixed at 60 mole %, the potential of the Sb(III)/Sb(O) couple increased about 0.43V at 27/sup 0/C. The persistence of a series of different arene radical cations in SbCl/sub 3/-BP(AlCl)/sub 4/ is compared with their persistance in molten SbCl/sub 3/-KCl.
Research Organization:
Oak Ridge National Lab., TN
DOE Contract Number:
W-7405-ENG-26
OSTI ID:
5940803
Journal Information:
J. Electrochem. Soc.; (United States), Journal Name: J. Electrochem. Soc.; (United States) Vol. 131:7; ISSN JESOA
Country of Publication:
United States
Language:
English

Similar Records

Electrochemical properties of the solvent SbCl/sub 3/-AlCl/sub 3/-N(1-butyl)pyridinium chloride and electrochemical and spectroelectrochemical studies of arene solutes
Journal Article · Sun Jul 01 00:00:00 EDT 1984 · J. Electrochem. Soc.; (United States) · OSTI ID:6211140
Electrochemical properties of the solvent SbCl/sub 3/-AlCl/sub 3/-N-(1-BUTYL)pyridinium chloride and electrochemical and spectroelectrochemical studies of the solute 9,10-dimethylanthracene
Conference · Sun May 01 00:00:00 EDT 1983 · Proc. - Electrochem. Soc.; (United States) · OSTI ID:6507638
Electrochemical properties of the solvent SbCl/sub 3/-AlCl/sub 3/-N-(1-butyl)pyridinium chloride and electrochemical and spectroelectrochemical studies of the solute 9,10-dimethylanthracene. [Oxidation of 9,10-dimethylanthracene to radical cation]
Conference · Fri Dec 31 23:00:00 EST 1982 · OSTI ID:5693194

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALUMINIUM CHLORIDES
ALUMINIUM COMPOUNDS
AMINES
AMMONIUM COMPOUNDS
ANTHRACENE
ANTIMONY CHLORIDES
ANTIMONY COMPOUNDS
AROMATICS
AZINES
CHEMICAL REACTIONS
CHEMISTRY
CHLORIDES
CHLORINE COMPOUNDS
CONDENSED AROMATICS
DATA
DECOMPOSITION
ELECTROCHEMISTRY
EUTECTICS
EXPERIMENTAL DATA
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
INFORMATION
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PERYLENE
PYRIDINES
PYRIDINIUM COMPOUNDS
QUATERNARY COMPOUNDS