Potential corrosion and degradation mechanisms of Zircaloy cladding on spent nuclear fuel in a tuff repository
A literature review and analysis were made of corrosion and degradation processes applicable to Zircaloy cladding on spent nuclear fuel in a tuff repository. In particular, lifetime sought for the Zircaloy is 10,000 years. Among the potential failure mechanisms examined were: oxidation by steam, air, and water, including the effects of ions whose presence is anticipated in the water; mechanical overload; stress (creep) rupture; stress-corrosion cracking (SCC); and delayed failure due to hydride cracking. The conclusion is that failure due to oxidation is not credible, although a few experiments are suggested to confirm the effect of aqueous fluoride on the Zircaloy cladding. Mechanical overload is not a problem, and failure from stress-rupture does not appear likely based on a modified Larson-Miller analysis. Analysis shows that delayed hydride cracking is not anticipated for the bulk of spent fuel pins. However, for a minority of pins under high stress, there is some uncertainty in the analysis as a result of: (1) uncertainty about crack depths in spent fuel claddings and (2) the effect of slow cooling on the formation of radially oriented hydride precipitates. Experimental resolution is called for. Finally, insufficient information is currently available on stress-corrosion cracking. While evidence is presented that SCC failure is not likely to occur, it is difficult to demonstrate this conclusively because the process is not clearly understood and data are limited. Further experimental work on SCC susceptibility is especially needed.
- Research Organization:
- Lawrence Livermore National Lab., CA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- W-7405-ENG-48
- OSTI ID:
- 59331
- Report Number(s):
- UCID--20172; ON: DE85003996
- Country of Publication:
- United States
- Language:
- English
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