POHC (principal organic hazardous constituent) analysis methods for hazardous-waste incineration. Volume 1, Part 1. Final report, April-December 1981

Technical Report · Sat Aug 01 00:00:00 EDT 1987

OSTI ID:5928823

James, R H; Finkel, J M; Dillon, H K; Miller, H C; Wensky, A K

This report gives preliminary data on methodology for candidate principal organic hazardous constituents (POHCs) that represent a variety of compound types, including alcohols, esters, chlorinated aliphatics and aromatics, carboxylic acids, aliphatic and aromatic amines, nitrated aromatics, nitrosamines, hydrazines, nitriles, organosulfur compounds, and polynuclear aromatics and heterocyclics. This work (and that under Contract 68-02-3696, Task 1) involved the evaluation of generalized GC/FID, GC/MS, and HPLC/UV methods for determining approximately 170 compounds from the approximately 400 compounds in Appendix VIII, Part 261, 40 CFR. However, the survey-analysis portion of waste characterization often targets specific compounds for determination in incinerator effluent that are not amenable to previously developed methods. Therefore, current research involves the development of specific GC/FID, GC/MS, and HPLC/UV methods for the determination of several of these compounds. The EPA has proposed regulations for owners and operators of facilities that treat hazardous wastes by incineration to ensure that these incinerators will be operated in an environmentally responsble manner. The primary criterion upon which the operational specifications are based is the destruction and removal efficiency (DRE) of the incinerator (= or > 99.99%).

• Research Organization: Southern Research Inst., Birmingham, AL (USA)
• OSTI ID: 5928823
• Report Number(s): PB-87-227286/XAB; SORI-EAS-86-1105
• Country of Publication: United States
• Language: English

Related Subjects

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
320305* -- Energy Conservation
Consumption
& Utilization-- Industrial & Agricultural Processes-- Industrial Waste Management
CHROMATOGRAPHY
COMBUSTION PRODUCTS
GAS ANALYSIS
GAS CHROMATOGRAPHY
HAZARDOUS MATERIALS
INCINERATORS
INDUSTRIAL WASTES
MATERIALS
ORGANIC COMPOUNDS
SAMPLING
SEPARATION PROCESSES
SOLID WASTES
SPECTROSCOPY
WASTES