Complex formation effects during the oxidation of cyclohexene with lead tetraacetate

Journal Article · Sat Mar 01 04:00:00 EST 1986 · Theor. Exp. Chem. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00944088· OSTI ID:5917970

Gutsulyak, R B; Serguchev, Yu A

The effect of complex formation between lead(IV) and trifluoroacetic or methane-sulfonic acid and chloride ion in acetic acid and Freon 113 on the oxidation of cyclohexene by lead tetraacetate was investigated. As a result of the reaction the ..beta..-chlorocyclohexyl esters of the corresponding acids are formed with high yields. The formation of the complexes Pb (OAc)/sub 4-n/L/sub n/ and Pb(OAc)/sub 4-(n+1)/L/sub n/Cl, where L = CF/sub 3/CO/sub 2/- or CH/sub 3/SO/sub 3/- with n = 1 or 2, was demonstrated by potentiometric titration. A scheme is proposed for the oxidation of cyclohexene with the participation of unlike-ligand complexes of Pb(IV).

• Research Organization: Institute of Organic Chemistry, Kiev, USSR
• OSTI ID: 5917970
• Journal Information: Theor. Exp. Chem. (Engl. Transl.); (United States), Journal Name: Theor. Exp. Chem. (Engl. Transl.); (United States) Vol. 21:5; ISSN TEXCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETATES
ACETIC ACID
ACETIC ACID ESTERS
ALKENES
CARBOXYLIC ACID ESTERS
CARBOXYLIC ACID SALTS
CARBOXYLIC ACIDS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORINATION
CHLORINE COMPOUNDS
CHROMATOGRAPHY
COMPLEXES
COMPLEXOMETRY
CYCLOALKENES
ESTERS
FREONS
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATION
HEXENES
HYDROCARBONS
INFRARED SPECTRA
LEAD COMPLEXES
LEAD COMPOUNDS
MONOCARBOXYLIC ACIDS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXIDATION
POTENTIOMETRY
SEPARATION PROCESSES
SPECTRA
SULFONIC ACID ESTERS
TITRATION
YIELDS