Complex formation effects during the oxidation of cyclohexene with lead tetraacetate

Journal Article · Sat Mar 01 00:00:00 EST 1986 · Theor. Exp. Chem. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00944088· OSTI ID:5917970

Gutsulyak, R B; Serguchev, Yu A

The effect of complex formation between lead(IV) and trifluoroacetic or methane-sulfonic acid and chloride ion in acetic acid and Freon 113 on the oxidation of cyclohexene by lead tetraacetate was investigated. As a result of the reaction the ..beta..-chlorocyclohexyl esters of the corresponding acids are formed with high yields. The formation of the complexes Pb (OAc)/sub 4-n/L/sub n/ and Pb(OAc)/sub 4-(n+1)/L/sub n/Cl, where L = CF/sub 3/CO/sub 2/- or CH/sub 3/SO/sub 3/- with n = 1 or 2, was demonstrated by potentiometric titration. A scheme is proposed for the oxidation of cyclohexene with the participation of unlike-ligand complexes of Pb(IV).

• Research Organization: Institute of Organic Chemistry, Kiev, USSR
• OSTI ID: 5917970
• Journal Information: Theor. Exp. Chem. (Engl. Transl.); (United States), Vol. 21:5; Other Information: Translated from Teor. Eksp. Khim.; 21: No.5, 567-572(Sep-Oct 1985)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ACETATES
CATALYTIC EFFECTS
ACETIC ACID
COMPLEXOMETRY
CHLORINE COMPOUNDS
CYCLOALKENES
OXIDATION
LEAD COMPLEXES
LEAD COMPOUNDS
SULFONIC ACID ESTERS
ACETIC ACID ESTERS
CHEMICAL REACTION YIELD
CHLORINATION
CHROMATOGRAPHY
FREONS
HEXENES
INFRARED SPECTRA
POTENTIOMETRY
ALKENES
CARBOXYLIC ACID ESTERS
CARBOXYLIC ACID SALTS
CARBOXYLIC ACIDS
CHEMICAL REACTIONS
COMPLEXES
ESTERS
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATION
HYDROCARBONS
MONOCARBOXYLIC ACIDS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
SEPARATION PROCESSES
SPECTRA
TITRATION
YIELDS
400201* - Chemical & Physicochemical Properties