Evidence for the C-N bond formation between an aldose and ethylenediamine on cobalt (III) complexes. Deuterium isotope effects on carbon-13 NMR chemical shifts
Journal Article
·
· J. Coord. Chem.; (United States)
The chemical shifts of the /sup 13/C signals originating from the ethylenediamine in the /sup 13/C NMR spectra of cobalt(III) complexes containing an N-glycoside derived from ethylenediamine and an aldose presume to be due to the formation of a new C-N bond are reported. Deuterium isotope effects on the /sup 13/C NMR spectra were found to be very helpful in spectra assignments and molecular structure determination. Evidence is presented for a structure involving a new C-N bond. 3 references, 1 figure, 1 table.
- Research Organization:
- Univ. of Tokyo (Japan)
- OSTI ID:
- 5913731
- Journal Information:
- J. Coord. Chem.; (United States), Journal Name: J. Coord. Chem.; (United States) Vol. 18:1-3; ISSN JCCMB
- Country of Publication:
- United States
- Language:
- English
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Journal Article
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· J. Am. Chem. Soc.; (United States)
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OSTI ID:5849142
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· J. Am. Chem. Soc.; (United States)
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· Journal of the American Chemical Society; (USA)
·
OSTI ID:5208219
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
CARBOHYDRATES
CARBON 13
CARBON ISOTOPES
CHEMICAL SHIFT
COBALT COMPLEXES
COMPLEXES
DEUTERIUM
EVEN-ODD NUCLEI
GLYCOSIDES
HYDROGEN ISOTOPES
ISOTOPE EFFECTS
ISOTOPES
LIGHT NUCLEI
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
CARBOHYDRATES
CARBON 13
CARBON ISOTOPES
CHEMICAL SHIFT
COBALT COMPLEXES
COMPLEXES
DEUTERIUM
EVEN-ODD NUCLEI
GLYCOSIDES
HYDROGEN ISOTOPES
ISOTOPE EFFECTS
ISOTOPES
LIGHT NUCLEI
MOLECULAR STRUCTURE
NMR SPECTRA
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES