Sorption and desorption of organic compounds by flyash
Thesis/Dissertation
·
OSTI ID:5893579
A sorbent treatment process has been developed which uses flyash as sorbent in the treatment of highly toxic and hazardous chemicals; these include: Alcohols, Aldehydes, Ketones and Aromatics. Batch, as well as dynamic, studies were performed, in different phases, during the investigation. Single and multiple solute systems were examined separately. The samples were analyzed using a Flame Ionization Detector Gas Chromatograph. The result of this study demonstrates that isolation/immobilization of the organic pollutants is technologically feasible by adsorbing the contaminants onto flyash. The residual carbon content of the flyash plays a very significant role during the treatment process. The sorption of the organic compounds onto flyash is believed to occur principally via the weak induction forces of London or dispersion forces which are the characteristics of the physical adsorption. The treatment efficiency depends on the characteristics of the solute, the sorbent and the solution. The existence of interaction and competition among the solutes, for adsorption sites, is clear in the case of a multiple solute system.
- Research Organization:
- New Jersey Inst. of Tech., Newark, NJ (USA)
- OSTI ID:
- 5893579
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
01 COAL, LIGNITE, AND PEAT
010800* -- Coal
Lignite
& Peat-- Waste Management
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
320305 -- Energy Conservation
Consumption
& Utilization-- Industrial & Agricultural Processes-- Industrial Waste Management
ADSORPTION
AEROSOL WASTES
ALCOHOLS
ALDEHYDES
AROMATICS
ASHES
CARBON
CHROMATOGRAPHY
EFFICIENCY
ELEMENTS
FLAME PHOTOMETRY
FLY ASH
GAS CHROMATOGRAPHY
HAZARDOUS MATERIALS
HYDROXY COMPOUNDS
KETONES
MANAGEMENT
MATERIALS
NONMETALS
ORGANIC COMPOUNDS
PHOTOMETRY
POLLUTANTS
PROCESSING
RESIDUES
SEPARATION PROCESSES
SORPTION
SORPTIVE PROPERTIES
SURFACE PROPERTIES
TOXICITY
WASTE MANAGEMENT
WASTE PROCESSING
WASTES
010800* -- Coal
Lignite
& Peat-- Waste Management
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
320305 -- Energy Conservation
Consumption
& Utilization-- Industrial & Agricultural Processes-- Industrial Waste Management
ADSORPTION
AEROSOL WASTES
ALCOHOLS
ALDEHYDES
AROMATICS
ASHES
CARBON
CHROMATOGRAPHY
EFFICIENCY
ELEMENTS
FLAME PHOTOMETRY
FLY ASH
GAS CHROMATOGRAPHY
HAZARDOUS MATERIALS
HYDROXY COMPOUNDS
KETONES
MANAGEMENT
MATERIALS
NONMETALS
ORGANIC COMPOUNDS
PHOTOMETRY
POLLUTANTS
PROCESSING
RESIDUES
SEPARATION PROCESSES
SORPTION
SORPTIVE PROPERTIES
SURFACE PROPERTIES
TOXICITY
WASTE MANAGEMENT
WASTE PROCESSING
WASTES