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Title: Copper removal from solid ferrous scrap

Technical Report ·
OSTI ID:5889874

As discussed in detail in the Appendix, copper is detrimental to the properties of steel. Copper is present in most forms of recycled scrap, such as bundles and shredded scrap. Typical levels of copper in these forms of scrap are 0.2 to 0.4%, whereas critical grades of steel require less than 0.1 and often 0.06% Cu. Therefore, these forms of scrap cannot be used alone to produce quality steels. Steelmakers must dilute the copper from lower quality scrap with expensive high quality scrap or direct reduced iron pellets. Currently there is no effective method for removing copper from scrap. The only proven method is improved physical separation which is labor intensive, expensive, and only marginally reduces the copper content. Chemical treatments, such as sulfide treatment of liquid metal and vacuum, are not effective as discussed in the Appendix in detail. Carnegie Mellon University developed a concept for removing copper from solid ferrous scrap at 900--1000{degrees}C using a FeS-Na{sub 2}S reagent. Small laboratory tests showed 90% of the Cu from simulated solid scrap could be removed. The major results of this study are summarized in this report. Details are given in the reports in the Appendix.

Research Organization:
Carnegie Mellon Univ., Pittsburgh, PA (USA). Center for Iron and Steel Making Research
Sponsoring Organization:
USDOE; USDOE, Washington, DC (USA)
DOE Contract Number:
FG02-88CE40875
OSTI ID:
5889874
Report Number(s):
DOE/CE/40875-2; ON: DE91010831
Country of Publication:
United States
Language:
English