Influence of the nature of solvent and reaction medium on kinetics and mechanism of hydrogenation of certain aromatic compounds on group VIII metals. VI. Fluctuations of stationary potential of the catalyst during hydrogenation of nitrobenzenes

Journal Article · Sat Aug 01 00:00:00 EDT 1987 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:5889300

Finkelshtein, A V; Anisimov, L N

The kinetics of hydrogenation of nitrobenzene and its derivatives on a skeletal nickel catalysts was studied with parallel observation of fluctuations of the potential of the catalyst during hydrogenation. It was found that the dependence of the logarithm of the hydrogenation rate constants of nitrobenzenes on the intensity of fluctuations of the catalyst potential is nonlinear.

• Research Organization: Siberian Technological Institute, Krasnoyarsk, USSR
• OSTI ID: 5889300
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Vol. 28:1; Other Information: Translated from Kinet. Katal.; 28: No. 1, 208-210(Jan-Feb 1987)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
NICKEL
CATALYTIC EFFECTS
ELECTRIC POTENTIAL
NITROBENZENE
HETEROGENEOUS CATALYSIS
HYDROGENATION
CHEMICAL REACTION KINETICS
ELECTROCATALYSTS
ELECTRON TRANSFER
FLUCTUATIONS
MATHEMATICAL MODELS
CATALYSIS
CATALYSTS
CHEMICAL REACTIONS
ELEMENTS
KINETICS
METALS
NITRO COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
REACTION KINETICS
TRANSITION ELEMENTS
VARIATIONS
400201* - Chemical & Physicochemical Properties