Free radicals formed in the reaction of 1H-1-oxo-2,4,6,8-tetrakis-(tert-butyl)phenoxazine and 1-hydroxy-2,4,6,8-tetrakis(tert-butyl)-phenoxazinyl radical with certain organometallic compounds

Journal Article · Fri Jul 10 00:00:00 EDT 1987 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00953845· OSTI ID:5889106

Karsanov, I V; Ivakhnenko, E P; Khandkarova, V S; Rubezhov, A Z; Okhlobystin, O Yu; Minkin, V I; Prokof'ev, A I; Kabachnik, M I

1H-1-Oxo-2,4,6,8-tetrakis(tert-butyl)phenoxazine undergoes ligand exchange reactions and behaves as a spin trap for metal-centered radicals, as a result of which stable paramagnetic complexes are formed with delocalization of the unpaired electron in the organic ligand. Paramagnetic complexes are also formed as the result of a reaction between potassium salt (IA) and triphenyl-tin and triphenyl-lead monochlorides.

• Research Organization: A.N. Nesmeyanov Institute of Organoelemental Compounds, Moscow, USSR
• OSTI ID: 5889106
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 36:1; ISSN BACCA
• Country of Publication: United States
• Language: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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ANGULAR MOMENTUM
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HEAVY NUCLEI
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INTERMEDIATE MASS NUCLEI
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ISOMERIC TRANSITION ISOTOPES
ISOTOPE EFFECTS
ISOTOPE RATIO
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ISOTOPIC EXCHANGE
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LEAD COMPLEXES
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MAGNETIC RESONANCE
MANGANESE COMPLEXES
MERCURY 201
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MOLYBDENUM 95
MOLYBDENUM 97
MOLYBDENUM COMPLEXES
MOLYBDENUM ISOTOPES
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PARTICLE PROPERTIES
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
RADICALS
RADIOISOTOPES
REACTION KINETICS
RESONANCE
RHENIUM 185
RHENIUM 187
RHENIUM COMPLEXES
RHENIUM ISOTOPES
SECONDS LIVING RADIOISOTOPES
SPIN
STABLE ISOTOPES
TIN 117
TIN 119
TIN COMPLEXES
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YEARS LIVING RADIOISOTOPES
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