Hydrogenation of n-butyraldehyde on copper-containing catalysts. I. Reaction kinetics in the steady-state region
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:5887875
The kinetics of the hydrogenation of n-butyraldehyde was investigated on copper-containing catalysts at 100-200/degree/C. A kinetic equation was found, kinetic isotope effects when H/sub 2/ was replaced by D/sub 2/ were measured, and a step-by-step scheme is offered; the scheme specifies surface interaction of the starting components with the addition of a second adsorbed hydrogen in the slow step.
- Research Organization:
- N.D. Zelinskii Institute of Organic Chemistry, Moscow (USSR)
- OSTI ID:
- 5887875
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 29:4; ISSN KICAA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ADSORPTION
ALDEHYDES
ALLOYS
ALUMINIUM ALLOYS
CALCIUM ALLOYS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COPPER ALLOYS
DEUTERIUM
DISSOCIATION
ELEMENTS
EQUATIONS
HYDROGEN
HYDROGEN ISOTOPES
HYDROGENATION
ISOTOPE EFFECTS
ISOTOPES
ISOTOPIC EXCHANGE
KINETIC EQUATIONS
KINETICS
LIGHT NUCLEI
NICKEL COMPOUNDS
NONMETALS
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
PROMOTERS
REACTION KINETICS
SORPTION
STABLE ISOTOPES
TRANSITION ELEMENT COMPOUNDS
ZINC ALLOYS
400201* -- Chemical & Physicochemical Properties
ADSORPTION
ALDEHYDES
ALLOYS
ALUMINIUM ALLOYS
CALCIUM ALLOYS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COPPER ALLOYS
DEUTERIUM
DISSOCIATION
ELEMENTS
EQUATIONS
HYDROGEN
HYDROGEN ISOTOPES
HYDROGENATION
ISOTOPE EFFECTS
ISOTOPES
ISOTOPIC EXCHANGE
KINETIC EQUATIONS
KINETICS
LIGHT NUCLEI
NICKEL COMPOUNDS
NONMETALS
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
PROMOTERS
REACTION KINETICS
SORPTION
STABLE ISOTOPES
TRANSITION ELEMENT COMPOUNDS
ZINC ALLOYS