Vinyl ethers containing an epoxy group. XVI. Reaction of glycidol vinyloxyethyl ether with acetals
Journal Article
·
· J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:5887668
In order to obtain branched acetals with epoxide groups (prospective monomers and intermediates) the authors investigated the reaction of acetaldehyde diethyl and di(1,1,3-trihydrotetrafluoropropyl) acetals with glycidol vinyloxyethyl ether. The addition of acetals to vinyl epoxy ethers was realized, and the first representative of compounds of this type, i.e., 9-glycidyloxy-6-ethoxy-4-methyl-3,7-dioxanonane, was obtained. It was also impossible to add a fluoroacetal to butyl vinyl ether (0.08-1.00 wt. % of catalyst CF/sub 3/COOH, BF/sub 3//times/ OEt/sub 2/, 20-80/degree/C, 0.5-3 h).
- Research Organization:
- Irkutsk Institute of Organic Chemistry (USSR)
- OSTI ID:
- 5887668
- Journal Information:
- J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 24:5; ISSN JOCYA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETALS
ALDEHYDES
BORON COMPOUNDS
BORON FLUORIDES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHLORIDES
CHLORINE COMPOUNDS
EPOXIDES
ETHERS
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
INFRARED SPECTRA
IRON CHLORIDES
IRON COMPOUNDS
KINETICS
MERCURY COMPOUNDS
MERCURY OXIDES
MONOMERS
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
REACTION KINETICS
SPECTRA
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
VINYL MONOMERS
400201* -- Chemical & Physicochemical Properties
ACETALS
ALDEHYDES
BORON COMPOUNDS
BORON FLUORIDES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHLORIDES
CHLORINE COMPOUNDS
EPOXIDES
ETHERS
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
INFRARED SPECTRA
IRON CHLORIDES
IRON COMPOUNDS
KINETICS
MERCURY COMPOUNDS
MERCURY OXIDES
MONOMERS
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
REACTION KINETICS
SPECTRA
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
VINYL MONOMERS