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Carbon dioxide in the Paleozoic atmosphere: Evidence from carbon-isotope composition of pedogenic carbonate

Journal Article · · Geology; (United States)
; ;  [1]
  1. Univ. of Tennessee, Knoxville (United States)

Stable carbon-isotope compositions of pedogenic carbonate occurring in three clay-rich vertic paleosols within Paleozoic red-bed successions in central Pennsylvania provide a record of past pedogenic environments and can be used to estimate CO{sub 2} pressure (P{sub CO{sub 2}}) of the Paleozoic atmosphere. The {delta}{sup 13}C values of carbonate nodules from paleosols in the deltaic lower Bloomsburg Formation (Upper Silurian) reflect the contribution of carbon from marine groundwater or fossils, coupled with low biological activity. The {delta}{sup 13}C values of carbonate rhizocretions from stratigraphically high paleosols in the Bloomsburg Formation, and in the alluvial Catskill (Upper Devonian) and Mauch Chunk (Upper Mississippian) Formations, suggest an extensive C{sub 3} flora and significant contribution of atmospheric CO{sub 2}. Paleozoic atmospheric CO{sub 2} levels inferred from {delta}{sup 13}C of pedogenic carbonate are significantly higher than present levels.

OSTI ID:
5877468
Journal Information:
Geology; (United States), Journal Name: Geology; (United States) Vol. 19:10; ISSN GLGYB; ISSN 0091-7613
Country of Publication:
United States
Language:
English