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Evaluating open-path FTIR spectrometer data using different quantification methods, libraries, and background spectra obtained under varying environmental conditions

Thesis/Dissertation ·
DOI:https://doi.org/10.2172/587725· OSTI ID:587725
 [1]
  1. Univ. of North Carolina, Chapel Hill, NC (United States)
Studies were performed to evaluate the accuracy of open-path Fourier Transform Infrared (OP-FTIR) spectrometers using a 35 foot outdoor exposure chamber in Pittsboro, North Carolina. Results obtained with the OP-FTIR spectrometer were compared to results obtained with a reference method (a gas chromatograph equipped with a flame ionization detector, GC-FID). Concentration results were evaluated in terms of the mathematical methods and spectral libraries used for quantification. In addition, the research investigated the effect on quantification of using different backgrounds obtained at various times during the day. The chemicals used in this study were toluene, cyclohexane, and methanol; and these were evaluated over the concentration range of 5-30 ppm.
Research Organization:
North Carolina Univ., Chapel Hill, NC (United States). Dept. of Environmental Sciences and Engineering
Sponsoring Organization:
USDOE Assistant Secretary for Environment, Safety, and Health
DOE Contract Number:
AC05-76OR00033
OSTI ID:
587725
Report Number(s):
DOE/OR/00033--T780; ON: DE97053591
Country of Publication:
United States
Language:
English