Vibrational predissociation spectra of (HF)/sub n/, n = 2--6

Journal Article · Sun Nov 01 00:00:00 EST 1981 · J. Chem. Phys.; (United States)

OSTI ID:5872674

Lisy, J M; Tramer, A; Vernon, M F; Lee, Y T

Using molecular beam techniques and a tunable infraredlaser, the vibrational predissociation spectra for (HF)/sub n/, n = 2 to 6, in the 3000 to 4000 cm/sup -1/ range are presented. The vibrational bands have been assigned to intramolecular HF stretching modes and combinations of intra- and intermolecular modes. The structures of (HF)/sub n/, n = 3 to 6, were found to be cyclic, i.e., each HF molecule is both a proton donor and acceptor.

• Research Organization: Materials and Molecular Research Division, Lawrence Berkeley Laboratory, University of California, Berkeley, California 94720
• OSTI ID: 5872674
• Journal Information: J. Chem. Phys.; (United States), Journal Name: J. Chem. Phys.; (United States) Vol. 75:9; ISSN JCPSA
• Country of Publication: United States
• Language: English

Related Subjects

640302* -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
BEAMS
CHEMICAL REACTIONS
DECOMPOSITION
DIMERS
ELECTROMAGNETIC RADIATION
ENERGY LEVELS
EXCITED STATES
HYDROFLUORIC ACID
HYDROGEN COMPOUNDS
INFRARED RADIATION
INORGANIC ACIDS
LASER RADIATION
MOLECULAR BEAMS
MOLECULAR STRUCTURE
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
RADIATIONS
VIBRATIONAL STATES