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Fate and effect of residual hydrocarbons in the landfarming of oily sludge

Thesis/Dissertation ·
OSTI ID:5869647
A long-term laboratory simulation of landfarming explored the fate of polynuclear aromatic hydrocarbon (PNA) components of oily sludges in soil. CO/sub 2/ evolution and periodic analyses for PNAs and total extractable hydrocarbon (HC) assessed biodegradation. Laboratory landfarming continued for 30 months, involving 7 sludge applications at 3-5 month intervals. A closure study simulating biodegradation processes in an inactive landfarm followed for an additional 12 months. A burst of CO/sub 2/ evolution followed each sludge addition that decreased to background levels with time. Analyses showed that 50-60% of applied HC remained, but these residues did not inhibit biodegradation. As a class, PNAs disappeared faster than total HC (85% biodegradation). This was due to the prevalence of readily biodegraded 3-4 ring PNAs versus persistent 5-6 ring PNAs. Straw amendments during the closure study failed to increase HC or PNA biodegradation. Ability of soil treated with oily sludge to support plant growth during revegetation of landfarm soil was assessed. Corn germination and growth were greatly reduced, whereas soybean emergence was totally inhibited. Phytotoxic components of DAF-treated soil were associated with asphaltic residues. These also appear to interfere with geotropic orientation of seedlings. Revegetation of landform soils will require long closure periods and/or especially hardy plant species.
OSTI ID:
5869647
Country of Publication:
United States
Language:
English