Electrochemistry of intercalation compounds of graphite
Conference
·
· Proc. - Electrochem. Soc.; (United States)
OSTI ID:5868947
As a semimetal, graphite can be either anodically oxidized or cathodically reduced to form crystalline intercalation compounds. Such materials are characterized by a delocalized charge on the benzenoid framework, corresponding counter-charge on ions intercalated from the electrolyte salt, with these inserted ions screened from one another by co-intercalated solvent molecules. These intercalation compounds of graphite are formally analogous to (radical) ions of aromatic hydrocarbons. The graphite compound most frequently used in batteries is poly (carbon monofluoride), which is a non-conducting covalent compound of graphite and fluorine.
- Research Organization:
- Exxon Corporate Research-Science Laboratories, Linden, NJ
- OSTI ID:
- 5868947
- Report Number(s):
- CONF-8308116-
- Conference Information:
- Journal Name: Proc. - Electrochem. Soc.; (United States) Journal Volume: 84-5
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
25 ENERGY STORAGE
250903* -- Energy Storage-- Batteries-- Materials
Components
& Auxiliaries
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400400 -- Electrochemistry
ANODES
CARBON
CARBON COMPOUNDS
CARBON FLUORIDES
CATHODES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
CLATHRATES
COVALENCE
ELECTRIC BATTERIES
ELECTRIC CHARGES
ELECTROCHEMICAL CELLS
ELECTROCHEMISTRY
ELECTRODES
ELECTROLYTES
ELEMENTAL MINERALS
ELEMENTS
FLUORIDES
FLUORINE COMPOUNDS
GRAPHITE
HALIDES
HALOGEN COMPOUNDS
MINERALS
NONMETALS
OXIDATION
REDUCTION
SALTS
YIELDS
250903* -- Energy Storage-- Batteries-- Materials
Components
& Auxiliaries
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400400 -- Electrochemistry
ANODES
CARBON
CARBON COMPOUNDS
CARBON FLUORIDES
CATHODES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMISTRY
CLATHRATES
COVALENCE
ELECTRIC BATTERIES
ELECTRIC CHARGES
ELECTROCHEMICAL CELLS
ELECTROCHEMISTRY
ELECTRODES
ELECTROLYTES
ELEMENTAL MINERALS
ELEMENTS
FLUORIDES
FLUORINE COMPOUNDS
GRAPHITE
HALIDES
HALOGEN COMPOUNDS
MINERALS
NONMETALS
OXIDATION
REDUCTION
SALTS
YIELDS