Heterometallic aluminum alkoxides. The characterization of [l brace]Mg[Al(OPr[sup i])[sub 4]][sub 2][r brace][sub n] and Mg[sub 2]Al[sub 3](OPr[sup i])[sub 13]
Journal Article
·
· Chemistry of Materials; (United States)
- Univ. of Hawaii, Honolulu (United States)
While [open quotes]Mg[Al(OPr[sup i])[sub 4]][sub 2][close quotes] has been used and is marketed as an oxide precursor, even the exact composition of this substance is uncertain. In fact, Mg[Al(OPr[sup i])[sub 4]][sub 2] is in equilibrium with its dimer, [l brace]Mg[Al(OPr[sup i])[sub 4]][sub 2][r brace][sub 2], and with Mg[sub 2]Al[sub 3](OPr[sup i])[sub 13]. The X-ray structure of Mg[sub 2]Al[sub 3](OPr[sup i])[sub 13] provides a basis to understand the more extended array in [l brace]Mg[Al(OPr[sup i])[sub 4]][sub 2][r brace][sub 2]. 19 refs., 1 fig.
- OSTI ID:
- 5865955
- Journal Information:
- Chemistry of Materials; (United States), Journal Name: Chemistry of Materials; (United States) Vol. 5:6; ISSN CMATEX; ISSN 0897-4756
- Country of Publication:
- United States
- Language:
- English
Similar Records
Incorporation of barium for the synthesis of heterometallic alkoxides: Synthesis and structures of (BaZr sub 2 (O sup i Pr) sub 10 ) sub 2 and Ba l brace Zr sub 2 (O sup i Pr) sub 9 r brace sub 2
Synthesis and characterization of new alkoxotitanates of yttrium, barium and copper: Single crystal X-ray diffraction structures of Cl{sub 2}Y(Ti{sub 2}(OPr{sup i}){sub 9}), (Ti(OPr{sup i}){sub 5})Ba(Ti{sub 2}(OPr{sup i}){sub 9}), and ClCu(Ti{sub 2}(OPr{sup i}){sub 9})
Application of the hydro(solvento)thermal technique to the synthesis of metal carbonyl chalcogenide clusters. 2. Synthesis and X-ray structures of [[l brace]Fe[sub 4]Te[sub 4](CO)[sub 10][r brace][sub 2](Te[sub 2])][sup 2[minus]] and [[l brace]Fe[sub 2]Se(CO)[sub 6][r brace][sub 2]Se[sub 2]][sup 2[minus]]
Journal Article
·
Wed Jul 24 00:00:00 EDT 1991
· Inorganic Chemistry; (United States)
·
OSTI ID:6109846
Synthesis and characterization of new alkoxotitanates of yttrium, barium and copper: Single crystal X-ray diffraction structures of Cl{sub 2}Y(Ti{sub 2}(OPr{sup i}){sub 9}), (Ti(OPr{sup i}){sub 5})Ba(Ti{sub 2}(OPr{sup i}){sub 9}), and ClCu(Ti{sub 2}(OPr{sup i}){sub 9})
Journal Article
·
Wed May 21 00:00:00 EDT 1997
· Inorganic Chemistry
·
OSTI ID:563869
Application of the hydro(solvento)thermal technique to the synthesis of metal carbonyl chalcogenide clusters. 2. Synthesis and X-ray structures of [[l brace]Fe[sub 4]Te[sub 4](CO)[sub 10][r brace][sub 2](Te[sub 2])][sup 2[minus]] and [[l brace]Fe[sub 2]Se(CO)[sub 6][r brace][sub 2]Se[sub 2]][sup 2[minus]]
Journal Article
·
Tue Mar 16 23:00:00 EST 1993
· Inorganic Chemistry; (United States)
·
OSTI ID:6646380