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Title: High pressure synthesis and study of magnetic and transport properties of Pb-substituted manganites with perovskite structure

Journal Article · · Materials Research Bulletin
;  [1];  [2]
  1. Academy of Sciences of Belarus, Minsk (Belarus). Inst. of Physics of Solids and Semiconductors
  2. Polish Academy of Sciences, Warsaw (Poland). Inst. of Physics

The stoichiometric La{sub 1{minus}x}Pb{sub x}MnO{sub 3} (x {le} 0.6) and La{sub 0.56}Pb{sub 0.44}MnO{sub 2.56}F{sub 0.44} as well as nonstoichiometric La{sub 1{minus}x}Pb{sub x}MnO{sub 3{minus}y} (x {le} 0.44) solid solutions with perovskite structure have been obtained under high pressure conditions. It was demonstrated that these compounds are ferromagnetic in a wide range of Pb concentrations and exhibit large magnetoresistance in spite of the absence of Mn{sup 4+} ions. It is supposed that magnetic ordering in these materials is governed by superexchange interaction via oxygen.

OSTI ID:
586007
Journal Information:
Materials Research Bulletin, Vol. 32, Issue 12; Other Information: PBD: Dec 1997
Country of Publication:
United States
Language:
English