Synthesis and characterization of a complete series of (MM'(dppm)/sub 2/(CH/sub 3/CN)/sub 2/)(BF/sub 4/)/sub 2/ complexes (M,M' = Ni, Pd, Pt)

Journal Article · Wed Jul 13 00:00:00 EDT 1988 · Inorg. Chem.; (United States)

DOI:https://doi.org/10.1021/ic00287a021· OSTI ID:5853062

Miedaner, A; DuBois, D L

A complete series of homo- and heterobimetallic complexes of the type (MM'(dppm)/sub 2/(CH/sub 3/CN)/sub 2/)(BF/sub 4/)/sub 2/ (M, M' = Ni, Pd, Pt; dppm = Ph/sub 2/PCH/sub 2/PPh/sub 2/) have been prepared by comproportionation of appropriate M(0) and M'(II) complexes. These complexes have been characterized by /sup 1/H NMR and /sup 31/P NMR spectroscopy. NMR evidence shows that the acetonitrile ligands are labile for all complexes containing nickel and palladium. For certain heterobimetallic complexes, a second isomer is observed involving one bridging and one chelating dppm ligand while preserving the metal-metal bond. 33 references, 3 figures, 1 table.

• Research Organization: Solar Energy Research Institute, Golden, CO (USA)
• OSTI ID: 5853062
• Journal Information: Inorg. Chem.; (United States), Vol. 27:14
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
HETEROCYCLIC COMPOUNDS
SYNTHESIS
NICKEL COMPLEXES
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PALLADIUM COMPLEXES
PLATINUM COMPLEXES
EXPERIMENTAL DATA
MOLECULAR STRUCTURE
NMR SPECTRA
PHOSPHORUS 31
PROTONS
BARYONS
COMPLEXES
DATA
ELEMENTARY PARTICLES
FERMIONS
HADRONS
INFORMATION
ISOTOPES
LIGHT NUCLEI
NUCLEI
NUCLEONS
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
PHOSPHORUS ISOTOPES
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation