Synthesis and characterization of a complete series of (MM'(dppm)/sub 2/(CH/sub 3/CN)/sub 2/)(BF/sub 4/)/sub 2/ complexes (M,M' = Ni, Pd, Pt)
Journal Article
·
· Inorg. Chem.; (United States)
A complete series of homo- and heterobimetallic complexes of the type (MM'(dppm)/sub 2/(CH/sub 3/CN)/sub 2/)(BF/sub 4/)/sub 2/ (M, M' = Ni, Pd, Pt; dppm = Ph/sub 2/PCH/sub 2/PPh/sub 2/) have been prepared by comproportionation of appropriate M(0) and M'(II) complexes. These complexes have been characterized by /sup 1/H NMR and /sup 31/P NMR spectroscopy. NMR evidence shows that the acetonitrile ligands are labile for all complexes containing nickel and palladium. For certain heterobimetallic complexes, a second isomer is observed involving one bridging and one chelating dppm ligand while preserving the metal-metal bond. 33 references, 3 figures, 1 table.
- Research Organization:
- Solar Energy Research Institute, Golden, CO (USA)
- OSTI ID:
- 5853062
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 27:14; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
BARYONS
COMPLEXES
DATA
ELEMENTARY PARTICLES
EXPERIMENTAL DATA
FERMIONS
HADRONS
HETEROCYCLIC COMPOUNDS
INFORMATION
ISOTOPES
LIGHT NUCLEI
MOLECULAR STRUCTURE
NICKEL COMPLEXES
NMR SPECTRA
NUCLEI
NUCLEONS
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PALLADIUM COMPLEXES
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PLATINUM COMPLEXES
PROTONS
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
BARYONS
COMPLEXES
DATA
ELEMENTARY PARTICLES
EXPERIMENTAL DATA
FERMIONS
HADRONS
HETEROCYCLIC COMPOUNDS
INFORMATION
ISOTOPES
LIGHT NUCLEI
MOLECULAR STRUCTURE
NICKEL COMPLEXES
NMR SPECTRA
NUCLEI
NUCLEONS
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PALLADIUM COMPLEXES
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PLATINUM COMPLEXES
PROTONS
SPECTRA
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES