Functionalized 13-crown-4, 14-crown-4, 15-crown-4, and 16-crown-4 compounds: synthesis and lithium ion complexation

Journal Article · Fri Dec 14 04:00:00 UTC 1984 · J. Org. Chem.; (United States)

DOI:https://doi.org/10.1021/jo00199a011· OSTI ID:5847545

Czech, B P; Babb, D A; Son, B; Bartsch, R A

Seven novel (benzyloxy)methyl-substituted crown ethers with four ring oxygens and 13-, 14-, 15-, and 16-membered polyether rings are synthesized and their lithium and sodium cation-binding abilities are assessed by solvent extraction of the aqueous alkali metal picrates. Strongest lithium ion complexation is observed with ((benzyloxy)methyl)-14-crown-4 compounds. 28 references, 1 figure, 2 tables.

• Research Organization: Texas Technological Univ., Lubbock
• DOE Contract Number: AS05-80ER10604
• OSTI ID: 5847545
• Journal Information: J. Org. Chem.; (United States), Journal Name: J. Org. Chem.; (United States) Vol. 49:25; ISSN JOCEA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400105 -- Separation Procedures
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ABSORPTION SPECTROSCOPY
ALCOHOLS
ALKALI METAL COMPLEXES
ALKALI METALS
AQUEOUS SOLUTIONS
AROMATICS
CHEMICAL EXPLOSIVES
CHEMICAL PREPARATION
CHEMICAL REACTION YIELD
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
COMPARATIVE EVALUATIONS
COMPLEXES
COMPLEXOMETRY
DATA
DEUTERIUM COMPOUNDS
DISPERSIONS
ELEMENTS
EXPERIMENTAL DATA
EXPLOSIVES
EXTRACTION
GLYCOLS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INFORMATION
INFRARED SPECTRA
LITHIUM
LITHIUM COMPLEXES
METALS
MIXTURES
NITRO COMPOUNDS
NMR SPECTRA
NUMERICAL DATA
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC POLYMERS
PHENOLS
PICRIC ACID
POLYETHYLENE GLYCOLS
POLYMERS
SEPARATION PROCESSES
SODIUM
SODIUM COMPLEXES
SOLUTIONS
SOLVENT EXTRACTION
SOLVENT PROPERTIES
SPECTRA
SPECTROSCOPY
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
YIELDS