Oil shale compaction experimental results
Technical Report
·
OSTI ID:5845896
Oil shale compaction reduces the void volume available for gas flow in vertical modified in situ (VMIS) retorts. The mechanical forces caused by the weight of the overlying shale can equal 700 kPa near the bottom of commercial retorts. Clear evidence of shale compaction was revealed during postburn investigation of the Rio Blanco retorts at the C-a lease tract in Colorado. Western Research Institute conducted nine laboratory experiments to measure the compaction of Green River oil shale rubble during retorting. The objectives of these experiments were (1) to determine the effects of particle size, (2) to measure the compaction of different shale grades with 12 to 25 percent void volume and (3) to study the effects of heating rate on compaction. The compaction recorded in these experiments can be separated into the compaction that occurred during retorting and the compaction that occurred as the retort cooled down. The leaner oil shale charges compacted about 3 to 4 percent of the bed height at the end of retorting regardless of the void volume or heating rate. The richer shale charges compacted by 6.6 to 22.9 percent of the bed height depending on the shale grade and void volume used. Additional compaction of approximately 1.5 to 4.3 percent of the bed height was measured as the oil shale charges cooled down. Compaction increased with an increase in void volume for oil shale grades greater than 125 l/Mg. The particle size of the oil shale brick and the heating rate did not have a significant effect on the amount of compaction measured. Kerogen decomposition is a major factor in the compaction process. The compaction may be influenced by the bitumen intermediate acting as a lubricant, causing compaction to occur over a narrow temperature range between 315 and 430/sup 0/C. While the majority of the compaction occurs early in the retorting phase, mineral carbonate decomposition may also increase the amount of compaction. 14 refs., 12 figs., 4 tabs.
- Research Organization:
- Western Research Inst., Laramie, WY (USA)
- DOE Contract Number:
- FC21-83FE60177
- OSTI ID:
- 5845896
- Report Number(s):
- DOE/FE/60177-0041; ON: DE86010015
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
04 OIL SHALES AND TAR SANDS
040401* -- Oil Shales & Tar Sands-- In Situ Methods
True & Modified
ALKANES
BITUMINOUS MATERIALS
CARBONACEOUS MATERIALS
CHEMICAL REACTORS
COMPACTING
DATA
DISTILLATION EQUIPMENT
ENERGY SOURCES
EQUIPMENT
EXPERIMENTAL DATA
FOSSIL FUELS
FUELS
HEATING RATE
HIGH TEMPERATURE
HYDROCARBONS
INFORMATION
MATERIALS
METHANE
MODIFIED IN-SITU PROCESSES
NUMERICAL DATA
OIL SHALES
ORGANIC COMPOUNDS
PARTICLE SIZE
RETORTS
SIZE
TEMPERATURE DEPENDENCE
TIME DEPENDENCE
YIELDS
040401* -- Oil Shales & Tar Sands-- In Situ Methods
True & Modified
ALKANES
BITUMINOUS MATERIALS
CARBONACEOUS MATERIALS
CHEMICAL REACTORS
COMPACTING
DATA
DISTILLATION EQUIPMENT
ENERGY SOURCES
EQUIPMENT
EXPERIMENTAL DATA
FOSSIL FUELS
FUELS
HEATING RATE
HIGH TEMPERATURE
HYDROCARBONS
INFORMATION
MATERIALS
METHANE
MODIFIED IN-SITU PROCESSES
NUMERICAL DATA
OIL SHALES
ORGANIC COMPOUNDS
PARTICLE SIZE
RETORTS
SIZE
TEMPERATURE DEPENDENCE
TIME DEPENDENCE
YIELDS