Principles of the interaction of dichlorobutenes with diols in solutions of copper(I) halides

Journal Article · Mon Jun 01 04:00:00 EDT 1987 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:5845869

Shlapak, M S; Brailovskii, S M; Temkin, O N

The reactions of 3,4- and 1,4-dichlorobutenes with 1,2-ethanediol, 1,2- and 1,3-propanediols, and 1,4-butanediol in the presence of CuCl were investigated under uniform conditions. It was shown that in the case of 1,2- and 1,3-diols, the conversion products of dichlorobutenes are cyclic ethers. The rate constants of the conversion of dichlorobutenes in diol medium were determined, and the mechanism is discussed.

• Research Organization: M. V. Lomonosov Moscow Institute of Fine Chemical Technology, USSR
• OSTI ID: 5845869
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 27:6; ISSN KICAA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALKENES
BUTANEDIOLS
BUTENES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHLORIDES
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINE COMPOUNDS
COPPER CHLORIDES
COPPER COMPOUNDS
COPPER HALIDES
ETHERS
GLYCOLS
HALIDES
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
HYDROGEN TRANSFER
HYDROXY COMPOUNDS
KINETICS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
REACTION KINETICS
TRANSITION ELEMENT COMPOUNDS
YIELDS