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Mechanical Modeling of Stress Generation During Cure of Encapsulating Resins

Conference · · Materials Research Society Symposia Proceedings
DOI:https://doi.org/10.1557/proc-225-177· OSTI ID:5844388
 [1];  [1];  [1];  [2];  [2]
  1. Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
  2. Univ. of Pittsburgh, PA (United States)

We have developed a numerical model for calculating stresses generated during cure of shrinking encapsulating resins. Mechanical modeling of polymer encapsulated electronic devices usually focusses on stress generated during cooling after cure. The stress developed during cure, due to shrinkage of the encapsulant, is normally neglected. That assumption is valid if both the shear and bulk moduli of the encapsulant at the cure temperature are negligible with respect to the moduli at lower temperatures. Our measurements on a model epoxy encapsulant show that the shear modulus during cure, varying from 0 to 6 MPa, is at least 100 times smaller than that at ambient temperature. In contrast, the bulk modulus at the cure temperature is only 2.5 times smaller. Since the bulk modulus during cure cannot be neglected, significant stress can be produced if volume shrinkage is constrained by a stiff mold or embedded elements. In fact, mechanical failure of encapsulating materials during cure has been evident in some of our experiments. Using measurements of shear and bulk moduli plus volume shrinkage as inputs to a finite element model, we have successfully predicted the shrinkage strains and stresses developed during cure of a model epoxy resin inside a cylindrical tube. Consideration of cure shrinkage stress has led to a process modification that appears to reduce mechanical failures in a real encapsulated device.

Research Organization:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC04-76DP00789
OSTI ID:
5844388
Report Number(s):
SAND--90-3033C; CONF-910406--4; ON: DE91011496
Journal Information:
Materials Research Society Symposia Proceedings, Journal Name: Materials Research Society Symposia Proceedings Vol. 225; ISSN 0272-9172
Publisher:
Springer Nature
Country of Publication:
United States
Language:
English

References (4)

The physical properties of bisphenol-A-based epoxy resins during and after curing journal June 1986
Apparatus for measuring pressure–volume–temperature relationships of polymers to 350 °C and 2200 kg/cm2 journal August 1976
Nonlinear Structural Analysis of Complex Electronic and Electromechanical Assemblies journal November 1987
Constitutive equation for cure-induced stresses in a viscoelastic material journal November 1990