Mechanism of methanol conversion over zeolite
Conference
·
· Prepr. Pap. - Am. Chem. Soc., Div. Fuel Chem.; (United States)
OSTI ID:5841473
Details of the reaction mechanisms of conversions of methanol to various alkanes and alkenes were investigated. A discussion of the autocatalytic phenomena of the conversion of methanol over ZSM-5 zeolite was included. The temperature dependence and acidity aspects of the reaction rate were discussed. Also the use of Nafion-H and heteropolyacids as catalysts of conversion was also included. A detailed description of the self-condensation of methyl iodine over Ag/sub 3/PW/sub 12/O/sub 40/ was given. The distribution of hydrocarbon products on the reaction at various temperatures, reaction times, and molar ratios of reactants was given in tabular form.
- Research Organization:
- Tokyo Inst. of Tech., Japan
- OSTI ID:
- 5841473
- Report Number(s):
- CONF-830303-
- Conference Information:
- Journal Name: Prepr. Pap. - Am. Chem. Soc., Div. Fuel Chem.; (United States) Journal Volume: 28:2
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
02 PETROLEUM
020500* -- Petroleum-- Products & By-Products
090121 -- Hydrocarbon Fuels-- Chemical Synthesis-- (1976-1989)
10 SYNTHETIC FUELS
ALCOHOLS
ALKANES
ALKENES
CATALYTIC EFFECTS
CHEMICAL REACTIONS
HALOGEN COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
INORGANIC ION EXCHANGERS
IODINE COMPOUNDS
ION EXCHANGE MATERIALS
KINETICS
MATERIALS
METHANOL
MINERALS
ORGANIC COMPOUNDS
PH VALUE
REACTION KINETICS
SILVER COMPOUNDS
TEMPERATURE DEPENDENCE
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPOUNDS
ZEOLITES
020500* -- Petroleum-- Products & By-Products
090121 -- Hydrocarbon Fuels-- Chemical Synthesis-- (1976-1989)
10 SYNTHETIC FUELS
ALCOHOLS
ALKANES
ALKENES
CATALYTIC EFFECTS
CHEMICAL REACTIONS
HALOGEN COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
INORGANIC ION EXCHANGERS
IODINE COMPOUNDS
ION EXCHANGE MATERIALS
KINETICS
MATERIALS
METHANOL
MINERALS
ORGANIC COMPOUNDS
PH VALUE
REACTION KINETICS
SILVER COMPOUNDS
TEMPERATURE DEPENDENCE
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPOUNDS
ZEOLITES