Mechanism of methanol conversion over zeolite

Conference · Sat Jan 01 00:00:00 EST 1983 · Prepr. Pap. - Am. Chem. Soc., Div. Fuel Chem.; (United States)

OSTI ID:5841473

Ono, Y

Details of the reaction mechanisms of conversions of methanol to various alkanes and alkenes were investigated. A discussion of the autocatalytic phenomena of the conversion of methanol over ZSM-5 zeolite was included. The temperature dependence and acidity aspects of the reaction rate were discussed. Also the use of Nafion-H and heteropolyacids as catalysts of conversion was also included. A detailed description of the self-condensation of methyl iodine over Ag/sub 3/PW/sub 12/O/sub 40/ was given. The distribution of hydrocarbon products on the reaction at various temperatures, reaction times, and molar ratios of reactants was given in tabular form.

• Research Organization: Tokyo Inst. of Tech., Japan
• OSTI ID: 5841473
• Report Number(s): CONF-830303-
• Journal Information: Prepr. Pap. - Am. Chem. Soc., Div. Fuel Chem.; (United States), Vol. 28:2; Conference: 185. American Chemical Society national meeting, Seattle, WA, USA, 20 Mar 1983
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
10 SYNTHETIC FUELS
METHANOL
CHEMICAL REACTIONS
ZEOLITES
CATALYTIC EFFECTS
ALKANES
ALKENES
IODINE COMPOUNDS
PH VALUE
REACTION KINETICS
SILVER COMPOUNDS
TEMPERATURE DEPENDENCE
TUNGSTEN COMPOUNDS
ALCOHOLS
HALOGEN COMPOUNDS
HYDROCARBONS
HYDROXY COMPOUNDS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
KINETICS
MATERIALS
MINERALS
ORGANIC COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
020500* - Petroleum- Products & By-Products
090121 - Hydrocarbon Fuels- Chemical Synthesis- (1976-1989)