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Title: High-purity silicon for solar cell applications

Journal Article · · J. Met.; (United States)
DOI:https://doi.org/10.1007/BF03354369· OSTI ID:5840229

Demonstration quantities of high-purity silicon were produced using high-purity quartz and chemically purified charcoal in a modified 50-kVA arc furnace. Impurities from carbon reducing materials were found to be the major source of contamination. Charcoal used for smelting can be purified to very low impurity levels by halogen treatment at temperatures above 2000/sup 0/C. However, the low silicon recovery with purified charcoal appears to be related to the low rate of the silicon-producing reaction between silicon carbide and silica in the high-temperature zone of the furnace. X-ray examination of the charcoal showed a clear structural change during high-temperature purification and this change may be used as a test for the suitability of a purification method in future work. Investigation is underway to define purer, low-cost, reactive reducing materials in order to meet the $10/kg solar-grade silicon cost in tonnage quantities. The arc-furnace process is considered to be a feasible process to meet this goal.

OSTI ID:
5840229
Journal Information:
J. Met.; (United States), Vol. 30:6
Country of Publication:
United States
Language:
English